Teledyne Oxygen Equipment BDS 3960 User Manual

OPERATING INSTRUCTIONS FOR  
MODEL BDS-3960  
Oxygen Analyzer  
P/N M71903  
9/04/02  
ECO # 02-232  
DANGER  
Toxic gases and or flammable liquids may be present in this monitoring system.  
Personal protective equipment may be required when servicing this instrument.  
Hazardous voltages exist on certain components internally which may persist  
for a time even after the power is turned off and disconnected.  
Only authorized personnel should conduct maintenance and/or servicing.  
Before conducting any maintenance or servicing, consult with authorized  
supervisor/manager.  
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Specific Model Information  
The instrument for which this manual was supplied may  
incorporate one or more options not supplied in the standard instrument.  
Commonly available options are listed below, with check boxes. Any  
that are incorporated in the instrument for which this manual is supplied  
are indicated by a check mark in the box.  
Instrument Serial Number: _______________________  
Options Included in the Instrument with the Above Serial Number:  
220 VAC: Instrument configured 200-240 VAC, 50/60Hz  
power  
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BDS 3960  
Safety Messages  
Your safety and the safety of others is very important. We have  
provided many important safety messages in this manual. Please read  
these messages carefully.  
A safety message alerts you to potential hazards that could hurt you  
or others. Each safety message is associated with a safety alert symbol.  
These symbols are found in the manual and inside the instrument. The  
definition of these symbols is described below:  
GENERAL WARNING/CAUTION: Refer to the  
instructions for details on the specific danger. These cautions  
warn of specific procedures which if not followed could cause  
bodily Injury and/or damage the instrument.  
CAUTION: HOT SURFACE WARNING: This warning is  
specific to heated components within the instrument. Failure  
to heed the warning could result in serious burns to skin and  
underlying tissue.  
WARNING: ELECTRICAL SHOCK HAZARD: Dangerous  
voltages appear within this instrument. This warning is  
specific to an electrical hazard existing at or nearby the  
component or procedure under discussion. Failure to heed this  
warning could result in injury and/or death from  
electrocution.  
Technician Symbol: All operations marked with this symbol  
are to be performed by qualified maintenance personnel only.  
NOTE: Additional information and comments regarding a  
specific component or procedure are highlighted in the form  
of a note.  
No  
Symbol  
CAUTION:  
THE ANALYZER SHOULD ONLY BE USED FOR THE  
PURPOSE AND IN THE MANNER DESCRIBED IN  
THIS MANUAL.  
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IF YOU USE THE ANALYZER IN A MANNER OTHER  
THAN THAT FOR WHICH IT WAS INTENDED,  
UNPREDICTABLE BEHAVIOR COULD RESULT  
POSSIBLY ACCOMPANIED WITH HAZARDOUS  
CONSEQUENCES.  
This manual provides information designed to guide you through  
the installation, calibration and operation of your new analyzer. Please  
read this manual and keep it available.  
Occasionally, some instruments are customized for a particular  
application or features and/or options added per customer requests.  
Please check the front of this manual for any additional information in  
the form of an Addendum which discusses specific information,  
procedures, cautions and warnings that may be peculiar to your  
instrument.  
Manuals do get lost. Additional manuals can be obtained from  
Teledyne at the address given in the Appendix. Some of our manuals are  
available in electronic form via the internet. Please visit our website at:  
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BDS 3960  
Table of Contents  
Safety Messages ..........................................................................iv  
Table of Contents.........................................................................vi  
List of Figures...............................................................................ix  
List of Tables ................................................................................xi  
Introduction .................................................................................13  
1.1 Overview  
13  
13  
13  
14  
16  
1.2 Typical Applications  
1.3 Main Features of the Analyzer  
1.4 Front Panel (Operator Interface)  
1.5 Rear Panel (Equipment Interface)  
Operational Theory .....................................................................18  
2.1 Introduction  
18  
18  
18  
21  
22  
22  
22  
23  
24  
24  
25  
26  
2.2 BDS Sensor  
2.2.1 Principles of Operation  
2.2.2 Gas Flow Rate  
2.2.3  
2.2.4  
2.2.5  
Gas Pressure  
Temperature effect  
Recovery from High Level Oxygen Exposure  
2.2.6 Background Gas Compatibility  
2.2.7 Stability  
2.2.8 Maintenance  
2.3 Sample System  
2.4 Electronics and Signal Processing  
Installation ...................................................................................30  
3.1 Unpacking the Analyzer 30  
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3.2 Mounting the Analyzer  
3.3 Rear Panel Connections  
30  
32  
32  
33  
34  
34  
39  
40  
41  
3.3.1  
3.3.2  
Gas Connections  
Electrical Connections  
3.3.2.1 Primary Input Power  
3.3.2.2 50-Pin Equipment Interface Connector  
3.4 Electrolyte Refill of BDS Sensor  
3.5 Testing the System  
3.6 Powering Up the System  
Operation .....................................................................................42  
4.1 Introduction  
42  
43  
44  
4.2 The Analyzer application  
4.3 The System Screen  
4.3.1 Communication Information and Calibration Parameters 44  
4.3.2 Setting Software Parameters: Filter, Gas Factor,  
Tmp. Coeff.  
4.3.2.1 The Digital Filter  
45  
46  
46  
47  
48  
49  
49  
50  
50  
51  
51  
53  
53  
55  
55  
4.3.2.2 The Gas Factor  
4.3.2.3 Temperature Coefficient  
4.3.2.4 Set Defaults  
4.4 Calibration of the Analyzer  
4.4.1  
Zero Cal  
4.4.1.1 Zero Failure  
4.4.2  
Span Cal  
4.4.2.1 Span Failure  
4.5 The Alarms Function  
4.6 The Range Function  
4.6.1  
4.6.2  
Setting the Analog Output Ranges  
Fixed Range Analysis  
4.8 Signal Output  
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4.9 Switching The Program Back To The Front  
56  
Maintenance.................................................................................58  
5.1 Routine Maintenance  
58  
58  
59  
60  
61  
62  
62  
62  
5.2 Adding Water to the BDS Sensor  
5.3 Fuse Replacement  
5.4 Battery Backup Replacement  
5.5 Reinstalling Application software to PPC.  
5.5 Major Internal Components  
5.6 Cleaning  
5.7 Troubleshooting  
Appendix......................................................................................66  
A-1  
Specifications  
66  
68  
69  
69  
70  
71  
A-2 Recommended 2-Year Spare Parts List  
A-3 Drawing List  
A-4 19-inch Relay Rack Panel Mount  
A-5 Application notes  
Material Safety Data Sheet  
Index.............................................................................................74  
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List of Figures  
Figure 1-1: BDS-3960 Front Panel................................................15  
Figure 1-2: Model BDS 3960 Rear Panel......................................17  
Figure 2.1: Cross Section of the BDS Oxygen Sensor.................20  
Figure 2.2: BDS sensor output at different gas flow rate...............21  
Figure 2-3: A simplified BDS Sample System ...............................22  
Figure 2.4 Typical Purge-down Curve After Air Saturation............23  
Figure 2.5: Adding DI Water to the BDS Sensor ..........................24  
Figure 2-6: Flow Diagram..............................................................26  
Figure 2-7: BDS 3960 Electronics Block Diagram.........................28  
Figure 3-1: Model BDS 3960 Front Panel .....................................31  
Figure 3-2: Required Assembly Drawer Clearance .......................31  
Figure 3-3: Rear Panel of the Model BDS 3960 ...........................32  
Figure 3-4: Equipment Interface Connector Pin Arrangement.......34  
Figure 3-5: Adding Electrolyte to the BDS Sensor.......................40  
Figure 4-1: Main Menu ..................................................................43  
Figure 4.2: Parameter Selection Box.............................................46  
Figure 4.3: Range Options List Box...............................................54  
Figure 4.4: Range Setup Screen...................................................54  
Figure 5.1 Adding Water into the BDS sensor...............................59  
Figure 5-2: Removing Fuse Block from Housing...........................60  
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Figure 5-3: Vacuum Degassing for the BDS Oxygen Sensor.......64  
Figure A-1: Single 19" Rack Mount (dimensions in mm) ...............69  
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List of Tables  
Table 3-1: Analog Output Connections .........................................35  
Table 3-2: Alarm Relay Contact Pins ............................................36  
Table 3-3: Remote Calibration Connections..................................37  
Table 3-4: Range ID Relay Connections.......................................39  
Table 4-1: Gas Factor for Selected Gases....................................46  
Table 4-2: Parameter Default Values ............................................48  
Table 4-2: Linear Output for a 0-100 ppm O2 Range...................55  
Table 4-3: Range ID Output ..........................................................56  
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DANGER  
COMBUSTIBLE GAS USAGE  
WARNING  
This is a general purpose instrument designed for usage in a  
nonhazardous area. It is the customer's responsibility to  
ensure safety especially when combustible gases are being  
analyzed since the potential of gas leaks always exist.  
The customer should ensure that the principles of operating  
of this equipment is well understood by the user. Misuse of  
this product in any manner, tampering with its components,  
or unauthorized substitution of any component may  
adversely affect the safety of this instrument.  
Since the use of this instrument is beyond the control of  
Teledyne, no responsibility by Teledyne, its affiliates, and  
agents for damage or injury from misuse or neglect of this  
equipment is implied or assumed.  
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Oxygen Analyzer  
Introduction  
Introduction  
1.1  
Overview  
The Teledyne Analytical Instruments Model BDS 3960 Oxygen  
Analyzer is a versatile instrument for detecting oxygen at the parts-per-  
billion (ppb) level in a variety of gases. This manual covers the Model  
BDS 3960 General Purpose flush-panel and/or rack-mount units only.  
These units are for indoor use in a non-hazardous environment.  
1.2  
Typical Applications  
A few typical applications of the Model BDS 3960 are:  
Monitoring inert gas blanketing  
Air separation and liquefaction  
Chemical reaction monitoring  
Semiconductor manufacturing  
Petrochemical process control  
Quality assurance  
Gas analysis certification.  
1.3  
Main Features of the Analyzer  
The Model BDS 3960 Oxygen Analyzer is sophisticated yet simple  
to use. The main features of the analyzer include:  
Pocket PC with Windows CE operating system used as a  
controller for analyzer functions.  
High resolution, accurate readings of oxygen content from  
low ppb levels through 100 ppm. Large, bright, meter  
readout.  
New BDS Sensing technology, patent pending.  
Versatile analysis over a wide range of applications.  
Microprocessor based electronics: 8-bit CMOS  
microprocessor with 32 kB RAM and 8 kB ROM for I/O  
operations.  
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Introduction  
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Three user definable output ranges (from 0-100 ppb through  
0-100 ppm) allow best match to users process and  
equipment, plus a fixed 100 ppm over range.  
Auto Ranging allows analyzer to automatically select the  
proper preset range for a given measurement. Manual  
override allows the user to lock on to a specific range of  
interest.  
Two adjustable concentration alarms and a system failure  
alarm.  
Two way RFI protection.  
Four analog outputs: two for measurement (0–1 VDC and  
Isolated 4–20 mA DC) and two for range identification.  
Convenient and versatile, steel, flush-panel or rack-  
mountable case with slide-out electronics drawer.  
1.4  
Front Panel (Operator Interface)  
The standard BDS 3960 is housed in a rugged metal case with all  
controls and displays accessible from the front panel. See Figure 1-1.  
The front panel has the pocket PC, a digital meter, an alphanumeric  
display, and a window for viewing the sample flowmeter.  
There are no keys to press on the front panel. All interface with  
the analyzer is done through the touchscreen of the pocket PC. The main  
functions on the touchscreen are listed below.  
System  
Perform system-related tasks  
(described in detail in chapter 4,  
Operation.).  
Span  
Span calibrate the analyzer.  
Zero calibrate the analyzer.  
Zero  
Alarms  
Set the alarm setpoints and  
attributes for Alarm 1 and Alarm 2.  
Range  
Quit  
Set up the 3 user definable ranges  
for the instrument.  
Quit analyzer application.  
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Introduction  
Figure 1-1: BDS-3960 Front Panel  
Digital Meter Display: The meter display is a Light Emitting Diode  
(LED) device that produces large, bright, 7-segment numbers that are  
legible in any lighting. It produces a continuous readout from 0-999.9  
ppb and then switches to a continuous ppm readout from 0-100.00 ppm.  
It is accurate across all analysis ranges without the discontinuity inherent  
in analog range switching.  
Flowmeter: Monitors the flow of gas past the sensor. Readout is 0.1 to  
2.0 standard liters per minute (SLPM) of nitrogen  
CAUTION:  
THE POWER CABLE MUST BE UNPLUGGED TO  
FULLY DISCONNECT POWER FROM THE  
INSTRUMENT. WHEN CHASSIS IS EXPOSED OR  
WHEN ACCESS DOOR IS OPEN AND POWER  
CABLE IS CONNECTED, USE EXTRA CARE TO  
AVOID CONTACT WITH LIVE ELECTRICAL  
CIRCUITS.  
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Introduction  
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Access Drawer: For access to the BDS Sensor And pressure regulator.  
The front panel slides out when the four thumb screws are loosened.  
Opening the interior gives access to most circuit boards too.  
1.5  
Rear Panel (Equipment Interface)  
The rear panel, shown in Figure 1-2, contains the gas and electrical  
connectors for external inlets and outlets. The connectors are described  
briefly here and in detail in Chapter 3 Installation. Except for gas, AC  
power, and RS-232 communications I/O, all user connections for analog  
output, alarms, calibration and remote probe contacts are available  
through the 50 pin equipment interface connector. User connections  
made at the rear panel include:  
Power Connection  
110 VAC power source (220 VAC  
optional.  
Gas Inlet and Outlet  
Moisture By-pass  
One inlet and one exhaust out.  
Additional vent line for condensate  
Analog Outputs  
0–1 VDC oxygen concentration plus  
0-1 VDC range ID, and isolated  
4–20 mA DC oxygen concentration  
plus 4-20 mA DC range ID.  
Alarm Connections  
Remote Probe  
2 concentration alarms and 1  
system alarm.  
Used in the BDS 3960 for  
controlling external solenoid  
valves only.  
Remote Span/Zero  
Calibration Contact  
Digital inputs allow external  
control of analyzer calibration.  
To notify external equipment that  
instrument is being calibrated and  
readings are not monitoring  
sample.•  
Range ID Contacts  
Four separate, dedicated, range  
relay contacts. Low, Medium,  
High, Cal.  
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Introduction  
Figure 1-2: Model BDS 3960 Rear Panel  
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Operational Theory  
BDS 3960  
Operational Theory  
2.1  
Introduction  
The analyzer is composed of four subsystems:  
BDS Sensor  
Sample System  
Pocket PC  
Electronic I/O Signal Processing and Display  
The sample system is designed to accept the sample gas and  
transport it through the analyzer without contaminating or altering the  
sample prior to analysis. The BDS Sensor is an electrochemical device  
that translates the amount of oxygen present in the sample into an  
electrical current. The Pocket PC processes the sensor signal and sends  
messages to the I/O electronics to correctly display oxygen value as well  
as control other signals to the customer interface. The Electronic I/O  
signal processing amplifies the sensor signal, digitizes the sensor reading  
and sends them to the pocket PC for processing. Then it receives  
commands from the pocket PC to manipulate signals for the customer  
interface.  
2.2  
BDS Sensor  
2.2.1 Principles of Operation  
The BDS oxygen sensor technology developed at Teledyne  
Analytical Instruments is a result of TAI’s heavy investment on R&D  
and expertise established during the half-century’s manufacturing of  
electrochemical oxygen sensor. It stands for Bipotentiostat Driven  
Sensor. A BDS oxygen sensor accurately translates the oxygen level in  
the sample gas into to an electrical current signal.  
A potentiostat contains three electrodes: a working electrode, a  
reference electrode and a counter electrode. A Bipotentiostat is a  
combination of two potentiostats that share the reference electrode and  
the counter electrode. The potential at the working electrode is precisely  
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Oxygen Analyzer  
Operational Theory  
controlled with respect to the reference electrode. The counter electrode  
is used to carry the current that flow through the sensor. A potentiostat is  
typically constructed with several operational amplifiers. The three  
electrodes in an electrochemical cell and the operational amplifiers in  
the potentiostat constitute a feedback-control loop. The potentiostat  
technology has been well accepted in the field of electrochemistry, and  
proven effective in eliminating polarization of the reference electrode  
and automatic compensating electric resistance in the cell.  
In a BDS oxygen sensor, the sensing electrode is a working  
electrode that is under precise potential control as discussed above. A  
stable sensing electrode potential is very critical for an oxygen sensor to  
achieve high stability, low noise and large dynamic range. The reference  
electrode in a BDS sensor is a Ag/Ag2O electrode which is well known  
for its stable electrode potential and compatibility with the KOH  
electrolyte in an oxygen sensor. The counter electrode is made of a  
Platinum wire.  
The sensing process involves electrochemical reactions inside the  
sensor. At the sensing electrode, oxygen is reduced at the controlled  
potential:  
O + 2H O + 4e- — 4OH-  
(1)  
>
2
2
There is no net electrochemical reaction at the reference electrode  
since it is connected to the high impedance input of the operation  
amplifier.  
The electrochemical reaction at the counter electrode is:  
4OH- — O + 2H O + 4e-  
(2)  
>
2
2
It is noteworthy that reaction (2) is reverse of the reaction (1). It is  
indicative of a net change of zero inside a BDS sensor throughout the sensing  
process. This feature produces a long-term stability for the BDS sensor.  
There are two resources of oxygen being reduced at the sensing  
electrode: from the sample gas and dissolved oxygen within the  
electrolyte. The oxygen molecules in the sample gas diffuse to the  
sensing electrode through a diffusion barrier (controlled diffusion) to  
produce a current signal which is proportional to the oxygen level in the  
sample gas. However, the dissolved oxygen in the electrolyte also  
diffuses through the electrolyte. It is reduced at the sensing electrode and  
produces a background current. This background current represents the  
detection limit of an oxygen sensor.  
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Operational Theory  
BDS 3960  
The main advantage of the BDS technology lies in the unique  
second potentiostat. It is designed to remove dissolved oxygen and other  
impurities in the electrolyte. It eliminates the internal background  
current which previously limited the detection process.  
The second potentiostat is located adjacent to the sensing electrode.  
It uses a novel material, Reticulated Vitreous Carbon (RVC) and precise  
control of the potential to remove the dissolved oxygen and impurities in  
the electrolyte efficiently. As the result, the BDS sensor achieves an  
outstanding feature of absolute zero output in the absence of oxygen.  
Figure 2.1: Cross Section of the BDS Oxygen Sensor  
Figure 2.1 shows the schematic of a BDS oxygen sensor. The  
sample gas enters the sensor through the gas inlet port and exits at the  
gas outlet. A portion of oxygen in the sample gas diffuses through the  
diffusion barrier to be reduced at the sensing electrode to form OH- in  
the electrolyte. OH- can move freely through the porous 2nd working  
electrode. At the counter electrode, OH- is oxidized back to oxygen.  
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Oxygen Analyzer  
Operational Theory  
While the 2nd working electrode allows OH- to move through, it  
prevents the dissolved oxygen from the top portion of the sensor to reach  
the sensing electrode. The reference electrode provides a potential  
reference for both the sensing electrode and the 2nd working electrode.  
NOTE: BDS technology and sensor is a patent pending  
technology of Teledyne Analytical Instruments in the  
United State of America as well as many foreign countries.  
To learn more about BDS technology, please visit TAI’s web page at  
To learn more about potentiostat, visit Electochemical Society’s web  
2.2.2 Gas Flow Rate  
The output from a BDS oxygen sensor is relatively insensitive to  
change of gas flow rate if operated in the range of 1 - 3 SCFH (in  
nitrogen). The output drops when the flow rate is below 1 SCFH. Figure  
2.2 is a typical curve showing the sensor outputs at different flow rate.  
Figure 2.2: BDS sensor output at different gas flow rate  
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Operational Theory  
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2.2.3 Gas Pressure  
The analyzer is equipped with a pressure regulator as shown in  
Figure 2-3. To access the pressure regulator, the front panel must be  
opened. The inlet pressure should be regulated anywhere between 4 to  
50 psig. The sensor is not affected by pressure changes in the inlet as  
long as the analyzer vents to atmosphere. If the analyzer is not vented to  
atmosphere, the downstream pressure must not exceed 10 inch of water.  
A clogged or restricted vent or excessive pressure will force gas into the  
electrolyte and cause damage to the BDS sensor.  
Oxygen Scrubber  
Vent  
Flowmeter  
Sample  
Inlet  
Span  
Inlet  
BDS Sensor  
Pressure Regulator  
Figure 2-3: A simplified BDS Sample System  
2.2.4 Temperature effect  
The raw output from a BDS oxygen sensor has a temperature  
coefficient about 0.25% / °C. That is an average value, it changes as  
temperature changes. This temperature effect is compensated by the  
software throughout the operation temperature range (5 – 40°C).  
2.2.5  
Recovery from High Level Oxygen Exposure  
The ambient air contains about 210,000,000 ppb (2.1 x 108)  
oxygen. Figure 2.4 is a typical purge-down curve for a new BDS sensor  
which had been air saturated. It is normal to take several hours, even  
days for an air saturated BDS to purge down to a low ppb level.  
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Operational Theory  
Figure 2.4 Typical Purge-down Curve After Air Saturation  
Shortening the air exposure will allow a faster sensor recovery.  
A typical BDS sensor will recover to 1 ppm in approximately 25  
minutes, to 100 ppb after 80 min, and 10 ppb in about 8 hours, after  
suffering a ten-minute exposure to air.  
2.2.6 Background Gas Compatibility  
The BDS oxygen sensor will work in inert gas backgrounds,  
including nitrogen, hydrogen, argon, helium and ethane. The sensor  
output, however, is different in different background gases. For example,  
the sensor output in a hydrogen background is twice as much as it would  
be in a nitrogen background. Therefore, it is recommended to calibrate the  
analyzer with an oxygen standard that has a similar background as the  
sample gas. If an oxygen standard is unavailable for a particular  
background, a Gas Factor which is determined at TAI could be used to  
correct the sensor output in different background (see section 4.3.9).  
Note: the gas flow meter in the analyzer is calibrated for air. The  
error for measuring nitrogen is usually negligible. But for  
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Operational Theory  
BDS 3960  
hydrogen, it reads 100% lower. For example, when the  
float ball in the flowmeter is at 0.5 SLPM, the actual flow  
rate of hydrogen is about 1 SLPM.  
The BDS oxygen sensor can tolerate exposure to acidic gases. Up  
to 0.2% CO2 has no effect to ppb level oxygen measurement.  
2.2.7 Stability  
The BDS sensor is essentially drift free. Typically a BDS sensor  
requires no re-calibration over an entire year period. However, there  
may be some intrusion to the zero during the maintenance. See next  
section for details.  
2.2.8 Maintenance  
The only maintenance required on the BDS sensor is to replenish  
distilled or de-ionized water every three to four months. It is not  
necessary to take the analyzer out of service while adding water to the  
sensor but caution should be taken to avoid spilling water on the PC  
boards or other area inside the analyzer.  
Figure 2.5: Adding DI Water to the BDS Sensor  
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Operational Theory  
There is a Max line and Min Line clearly marked on the BDS sensor  
body. It is a good practice to check the electrolyte level every month and add  
de-ionized water into the sensor whenever it is convenient.  
When running dry gas through the sensor, the gas carries out moisture  
from the sensor. Therefore, the electrolyte (10% KOH in water) inside the  
sensor is gradually concentrated during the sensor operation. It typically takes  
about four months for the electrolyte level to drop from the Max line to Min  
line. When adding water to increase the electrolyte level from the Min line to  
the Max line, it is typical that the oxygen reading will drift down about 10  
ppb in an hour. If the oxygen content in the sample gas is very close to zero,  
the analyzer may display a negative reading during this period. The sensor  
will recover by itself during the following week. This drift-down then  
recover-back phenomenon is caused by the quick dilution of the electrolyte  
and re-establishment of a new equilibrium inside the sensor. To minimize  
this effect, add a small amount of water each time and do this before the  
electrolyte level reaches the Min line.  
2.3  
Sample System  
The sample system delivers gases to the BDS sensor from the  
analyzer rear panel inlet. Depending on the mode of operation either  
sample or calibration gas is delivered.  
The Model BDS 3960 sample system is designed and fabricated to  
ensure that the oxygen concentration of the gas is not altered as it travels  
through the sample system.  
The sample system for the standard instrument incorporates 1/4" VCR  
fittings for sample inlet, span inlet, and vent and Swagelock fittings for  
instrument air tube connections at the rear panel. The sample or calibration  
gas that flows through the system is monitored by a flowmeter downstream  
from the sensor.  
Figure 2-6 represents the flow diagram of the sampling system. In  
the standard instrument, span gases can be connected to its own  
separate inlet port. Solenoid valves are controlled by the software to  
switch the proper gas when the analyzer enters the span mode. Zero gas  
is generated internally when the sample gas is re-routed to go through an  
oxygen scrubber before it is fed to the sensor. The life of the oxygen  
sensor depends in two main factors: flow rate, oxygen impurity being  
scrubbed. Thus, the life of the scrubber can vary depending on the  
sample gas being used to zero the analyzer. It is recommended to change  
the oxygen scrubber every two years. Use this as a guideline only.  
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Operational Theory  
BDS 3960  
Note that instrument air at a pressure of 70 to 80 psig is needed to  
activate the proper valves.  
Figure 2-6: Flow Diagram  
2.4  
Electronics and Signal Processing  
The Model BDS 3960 Oxygen Analyzer uses an 8051  
microcontroller with 32 kB of RAM and 8 kB of ROM to control signal  
processing,, input/output, and display functions for the analyzer. Most of  
the processing power and decision making is done by the software  
running on the pocket PC (PPC). System power is supplied from a  
universal power supply module designed to be compatible with any  
international power source.  
The signal processing electronics including the microprocessor,  
analog to digital, and digital to analog converters are located on the I/O  
board at the bottom of the case. The preamplifier board is mounted on  
top of the I/O board. These boards are accessible by sliding the front out.  
Figure 2-7 shows a block diagram of the analyzer electronics.  
In the presence of oxygen the sensor generates a current. A current  
to voltage amplifier converts this current to a voltage which is further  
amplified in the second stage amplifier.  
The output from the second stage amplifier is sent to an 12 bit  
analog to digital converter that is located in the same chip as the  
microprocessor. The amplifier board also reads the ambient temperature  
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as the signal is passed to a second channel of the analog to digital  
converter.  
The raw counts of the analog to digital converter for both the  
oxygen sensor amplifier and temperature amplifier are sent to the PPC  
via RS232 interface once every second along with a status byte. The  
PPC performs processing on this data to calculate oxygen concentration,  
temperature, as well as decisions regarding the condition of the alarm  
contacts, range, amplifier gain, solenoid control, and the analog output  
required. After processing, the PPC sends a message back to I/O board,  
via RS232, with commands for all the I/O functions. The 8051  
microprocessor in the I/O board evaluates this data and the appropriate  
control signals are directed to the LED display, alarms contacts, range  
ID contacts, and digital to analog converter. The analog to digital  
converter is a 12 bit device located in the microprocessor IC. The output  
of the digital to analog converter with the help of some support  
electronics produces the 4-20 mA DC and the 0-1 VDC analog  
concentration signal outputs.  
Signals from the power supply are also monitored, and through the  
microprocessor, the system failure alarm is activated if a malfunction is  
detected. Failure to communicate with the PPC will also trigger the  
System alarm.  
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BDS 3960  
Temperature  
Sensor  
Amplifiers  
BDS  
Sensor  
ADC  
Alarm 1  
Alarm 2  
LED  
Display  
8051 processor  
DAC  
System  
Alarm  
Other  
Outputs  
UART  
0-1 VDC and  
4-20 ma  
support  
electronics  
Pocket  
PC  
Figure 2-7: BDS 3960 Electronics Block Diagram  
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Installation  
BDS 3960  
Installation  
Installation of the Model BDS 3960 Analyzer includes:  
Unpacking  
Mounting  
Gas connections  
Electrical connections  
Filling the Sensor with Electrolyte.  
Testing the system.  
3.1  
Unpacking the Analyzer  
Although the analyzer is shipped complete, certain parts, such as  
the electrolyte, are wrapped separately to be installed on site as part of  
the installation. Carefully unpack the analyzer and inspect it for damage.  
Immediately report any damage or shortages to the shipping agent.  
3.2  
Mounting the Analyzer  
The Model BDS 3960 is for indoor use in a general purpose area. It  
is NOT for hazardous environments of any type.  
The standard model is designed for flush panel mounting. Figure 3-1  
is an illustration of the BDS 3960 standard front panel and mounting  
bezel. There are four mounting holes—one in each corner of the rigid  
frame. The drawings section in the rear of this manual contains outline  
dimensions and mounting hole spacing diagrams.  
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Figure 3-1: Model BDS 3960 Front Panel  
Access to the electronics, the sensor, and sampling system is  
accomplished by loosening the thumbscrews on the front of the  
analyzer. The whole assembly will slide out toward the front. Allow  
clearance for the assembly to slide out when maintenance is required.  
Leave clearance of about 20 inches so that whole assembly can be pulled  
out of its case. See Figure 3-2.  
20 inch  
clearanc  
Figure 3-2: Required Assembly Drawer Clearance  
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3.3  
Rear Panel Connections  
Figure 3-3 shows the Model BDS 3960 rear panel. There are ports  
for gas inlet and outlet, power, communication, and analog  
concentration output.  
Figure 3-3: Rear Panel of the Model BDS 3960  
3.3.1 Gas Connections  
The unit is manufactured with1/4 inch VCR fittings with the  
exception of instrument air fitting. All of the gas connections are  
located on the rear of the analyzer. For all VCR fittings, insert a gasket  
(TAI PN G284) between the fittings and tighten the female and male  
nuts until fingertight; then by holding the male nut with a wrench,  
tighten the female nut with a second wrench an additional 1/6 turn.  
SAMPLE IN: The gas of interest connections are made at the SAMPLE  
IN and EXHAUST OUT connections. For zero calibration, the sample gas  
is rerouted through an oxygen scrubber to supply oxygen-free zero cal  
gas. A VCR fitting is provided for the inlet connection.  
The inlet gas pressure should be regulated to pressures between 5 to  
50 psig so that the internal regulator can be adjusted to maintain a flow  
between 0.5 to 1.0 SLPM. If pressure is too low, the flow will drop  
below 0.5 SLPM which is below the threshold to which the sensor is  
sensitive (see Section 2.2.2). If pressure is too high, it will force gas into  
the electrolyte and cause damage to the sensor. The internal pressure  
regulator is helpful if the sample pressure varies.  
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If greater sample flow is required for improved response time,  
install a bypass in the sampling system upstream of the analyzer input.  
SPAN IN: Span gas is connected to this port and it is automatically  
routed by solenoid valves when the analyzer goes into the span mode. Its  
pressure should be about the same as the inlet pressure of the sample  
gas. This will ensure that flow remains unchanged when switching  
between calibration and sample gases and this in turn increases accuracy  
of the calibration.  
EXHAUST OUT: Exhaust connections must be consistent with the  
hazard level of the constituent gases. Check Local, State, and Federal  
laws, and ensure that the exhaust stream vents to an appropriately  
controlled area, if required.  
CAUTION: CONNECT VENT LINES TO 1/4” OR LARGER  
DIAMETER TUBING.  
AIR INLET: The solenoid valves of the sampling system need air  
pressure to actuate them. Use the compression fitting and 1/4” tubing to  
connect instrument air (compressed air) with pressure in the range of 70  
to 80 psig.  
CAUTION: PRESSURE HIGHER THAN 100 PSIG CAN DAMAGE  
THE SOLENOID VALVES.  
3.3.2 Electrical Connections  
For safe connections, no uninsulated wiring should be able to come  
in contact with fingers, tools or clothing during normal operation.  
CAUTION:  
USE SHIELDED CABLES. ALSO, USE PLUGS THAT  
PROVIDE EXCELLENT EMI/RFI PROTECTION. THE  
PLUG CASE MUST BE CONNECTED TO THE CABLE  
SHIELD, AND IT MUST BE TIGHTLY FASTENED TO  
THE ANALYZER WITH ITS FASTENING SCREWS.  
ULTIMATELY, IT IS THE INSTALLER WHO ENSURES  
THAT THE CONNECTIONS PROVIDE ADEQUATE  
EMI/RFI SIELDING.  
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3.3.2.1 PRIMARY INPUT POWER  
The power cord receptacle and fuse block are located in the same  
assembly. Insert the power cord into the power cord receptacle.  
CAUTION:  
POWER IS APPLIED TO THE INSTRUMENT'S  
CIRCUITRY AS LONG AS THE INSTRUMENT IS  
CONNECTED TO THE POWER SOURCE.  
The power supply requires 100–120 VAC, 50/60 Hz power source.  
Fuse Installation: The fuse block, at the right of the power cord  
receptacle, accepts US or European size fuses. A jumper replaces the  
fuse in whichever fuse receptacle is not used. Fuses may not be installed  
at the factory. Be sure to install the proper fuse as part of installation.  
(See Fuse Replacement in Chapter 5, Maintenance.)  
3.3.2.2 50-PIN EQUIPMENT INTERFACE CONNECTOR  
Figure 3-4 shows the pin layout of the Equipment Interface  
connector. The arrangement is shown as seen when the viewer faces the  
rear panel of the analyzer. The pin numbers for each input/output  
function are given where each function is described in the paragraphs  
below.  
Figure 3-4: Equipment Interface Connector Pin Arrangement  
Analog Outputs: There are four DC output signal pins—two pins per  
output. For polarity, see Table 3-1. The outputs are:  
0–1 VDC % of Range: Voltage rises linearly with increasing  
oxygen, from 0 V at 0 ppm to 1 V at  
full scale ppm. (Full scale = 100% of  
programmable range.)  
0–1 VDC Range ID:  
0.25 V = Low Range, 0.5 V = Medium  
Range, 0.75 V = High Range, 1 V =  
100ppm.  
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4–20 mA DC % Range: Current increases linearly with  
increasing oxygen, from 4 mA at 0  
ppm to 20 mA at full scale ppm. (Full  
scale = 100% of programmable range.)  
4–20 mA dc Range ID: 8 mA = Low Range, 12 mA = Medium  
Range, 16 mA = High Range, 20 mA  
= 100ppm.  
Table 3-1: Analog Output Connections  
Pin  
3
Function  
+ Range ID, 4-20 mA, floating  
– Range ID, 4-20 mA, floating  
+ % Range, 4-20 mA, floating  
– % Range, 4-20 mA, floating  
+ Range ID, 0-1 V dc  
4
5
6
8
23  
– Range ID, 0-1 V dc, negative ground  
+ % Range, 0-1 V dc  
24  
7
– % Range, 0-1 V dc, negative ground  
Alarm Relays: The nine alarm-circuit connector pins connect to the  
internal alarm relay contacts. Each set of three pins provides one set of  
Form C relay contacts. Each relay has both normally open and normally  
closed contact connections. The contact connections are shown in Table  
3-2. They are capable of switching up to 3 amperes at 250 VAC into a  
resistive load. The connectors are:  
Threshold Alarm 1:  
Can be configured as high (actuates when concentration  
is above threshold), or low (actuates when concentration  
is below threshold).  
Can be configured as failsafe or nonfailsafe.  
Can be configured as latching or nonlatching.  
Can be configured out (defeated).  
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Threshold Alarm 2:  
Can be configured as high (actuates when concentration  
is above threshold), or low (actuates when concentration  
is below threshold).  
Can be configured as failsafe or nonfailsafe.  
Can be configured as latching or nonlatching.  
Can be configured out (defeated).  
System Alarm:  
Actuates when DC power supplied to circuits is  
unacceptable in one or more parameters. Permanently  
configured as failsafe and latching. Cannot be defeated.  
Actuates if communication with PPC fails.  
Further detail can be found in Chapter 4, Section 4-5.  
Table 3-2: Alarm Relay Contact Pins  
Pin  
45  
28  
46  
42  
44  
43  
36  
20  
37  
Contact  
Threshold Alarm 1, normally closed contact  
Threshold Alarm 1, moving contact  
Threshold Alarm 1, normally open contact  
Threshold Alarm 2, normally closed contact  
Threshold Alarm 2, moving contact  
Threshold Alarm 2, normally open contact  
System Alarm, normally closed contact  
System Alarm, moving contact  
System Alarm, normally open contact  
Digital Remote Cal Inputs: Accept 0 V (off) or 24 V dc (on) inputs for  
remote control of calibration. (See Remote Calibration Protocol below.)  
See Table 3-3 for pin connections.  
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Zero:  
Floating input—5 to 24 V input across the + and – pins  
puts the analyzer into the Zero mode. Either side may be  
grounded at the source of the signal. 0 to 1 volt across the  
terminals allows Zero mode to terminate when done. A  
synchronous signal must open and close the external zero  
valve appropriately. See Remote Probe Connector. (The  
–C option internal valves operate automatically).  
Span:  
Floating input—5 to 24 V input across the + and – pins  
puts the analyzer into the Span mode. Either side may be  
grounded at the source of the signal. 0 to 1 volt across the  
terminals allows Span mode to terminate when done. A  
synchronous signal must open and close external span  
valve appropriately. See Figure 3-5 Remote Probe  
Connector. (The –C option internal valves operate  
automatically.)  
Cal Contact:  
This relay contact is closed while analyzer is spanning  
and/or zeroing. (See Remote Calibration Protocol below.)  
Table 3-3: Remote Calibration Connections  
Pin  
9
Function  
+ Remote Zero  
– Remote Zero  
+ Remote Span  
– Remote Span  
Cal Contact  
11  
10  
12  
40  
41  
Cal Contact  
Remote Calibration Protocol: To properly time the Digital Remote Cal  
Inputs to the Model BDS 3960 Analyzer, the customer's controller must  
monitor the Cal Relay Contact.  
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When the contact is OPEN, the analyzer is analyzing, the  
Remote Cal Inputs are being polled, and a zero or span command  
can be sent.  
When the contact is CLOSED, the analyzer is already calibrating. It  
will ignore your request to calibrate, and it will not remember that  
request.  
Once a zero or span command is sent, and acknowledged (contact  
closes), release it. If the command is continued until after the zero or  
span is complete, the calibration will repeat and the Cal Relay Contact  
(CRC) will close again.  
For example:  
1) Test the CRC. When the CRC is open, Send a zero command  
until the CRC closes (The CRC will quickly close.)  
2) When the CRC closes, remove the zero command.  
3) When CRC opens again, send a span command until the  
CRC closes. (The CRC will quickly close.)  
4) When the CRC closes, remove the span command.  
When CRC opens again, zero and span are done, and the sample is  
being analyzed.  
Note: The Remote Valve connections (described below) provides  
signals to ensure that the zero and span gas valves will be  
controlled synchronously.  
Range ID Relays: There are four dedicated Range ID relay contacts.  
The first three ranges are assigned to relays in ascending order—Low  
range is assigned to Range 1 ID, Medium range is assigned to Range 2  
ID, and High range is assigned to Range 3 ID. The fourth range is  
reserved for the over Range (100 ppm). Table 3-4 lists the pin  
connections. There is contact opening to indicate what range the  
analyzer is on. The contacts open when the analyzer is on that range.  
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Table 3-4: Range ID Relay Connections  
Pin  
21  
38  
22  
39  
19  
18  
34  
35  
Function  
Range 1 ID Contact  
Range 1 ID Contact  
Range 2 ID Contact  
Range 2 ID Contact  
Range 3 ID Contact  
Range 3 ID Contact  
Range 4 ID Contact (Over range)  
Range 4 ID Contact (Over range)  
3.4  
Electrolyte Refill of BDS Sensor  
The BDS sensor is shipped dry. It must be filled with the  
electrolyte before operation. The electrolyte is a caustic solution (10%  
KOH), supplied in five 50 ml bottles. Review the Material Safety Data  
Sheet (MSDS) in Section A-6 before handling the electrolyte.  
To refill the BDS sensor:  
1. Loosen the thumb screws on the front and slide the drawer  
halfway out.  
2. Unscrew the sensor cap and disconnect sensor cable from the  
BDS sensor.  
3. Pour the electrolyte from the five small bottles into a larger  
container.  
4. Sparge the electrolyte with nitrogen gas at a flow of 100 CCM  
for about 1/2 hour then pour into the provided wash bottle.  
5. Ref. to Figure 3.5 for the method of adding electrolyte to the  
sensor. It is important that as the sensor is being filled with the  
electrolyte, filling is accomplished without trapping gas bubbles  
in the lower part of the sensor.  
6. Squirt electrolyte content into the sensor. Do it slowly until the  
bottom parts of the sensor are fully immersed in the electrolyte.  
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7. Pour the rest of the electrolyte into the sensor. Gas bubbles in the  
top portion of the sensor do not affect the sensor performance.  
One bottle of electrolyte is sufficient to rise the electrolyte level  
to the MAX line. For the rest of sensor life, no further electrolyte  
addition is needed.  
8. Install the sensor cap.  
9. Do not connect the sensor's electric connector at this stage.  
Figure 3.5: Adding Electrolyte to the BDS Sensor  
3.5  
Testing the System  
Before plugging the instrument into the power source:  
Check the integrity and accuracy of the gas connections.  
Make sure there are no leaks. Gas connection should allow  
for some movement on the drawer assembly so that the  
pressure regulator and the sensor connector cable can be  
reached inside.  
Check the integrity and accuracy of the electrical  
connections. Make sure there are no exposed conductors  
Check pressure of sample gas as well as instrument air. Set  
the internal pressure regulator fully counterclockwise.  
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3.6  
Powering Up the System  
Before powering up the system, set the pressure regulator to  
minimum to prevent damage due to incorrect setting. Power up the  
system by turning on the switch on the rear. Then turn on the PPC by  
pressing the button on its left side. Make sure that the Analyzer  
application is running. If the Analyzer application is not running, launch  
it by following the these steps:  
Tap on Start found on the taskbar either at the bottom or the  
top of the LCD screen of the PPC to pull down a menu.  
Tap on Programs to bring up the programs browser.  
Then tap on the Analyzer icon found in the browser. This  
should launch the Analyzer application.  
Adjust the internal pressure regulator until gas flow is in the  
middle of the flowmeter, around the 1 SLPM mark.  
Purge the sensor for about 15 minutes, then proceed to  
connect the sensor cable.  
Close the assembly drawer and tighten the thumb screws.  
Purge the analyzer until readings decrease below 50 ppb.  
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Maintenance  
BDS 3960  
Operation  
4.1  
Introduction  
Once the analyzer has been installed, it can be configured for your  
application. To do this you will:  
Set system parameters:  
Calibrate the instrument.  
Define the three user-selectable analysis ranges, then choose  
autoranging or select a fixed range of analysis, as required.  
Set alarm setpoints, and modes of alarm operation (latching,  
failsafe, etc).  
Before you configure your BDS 3960, these default values are in  
effect:  
Ranges: LO = 100ppb , MED = 1000 ppb,  
HI = 10 ppm, Over-Range = 100  
ppm  
Auto Ranging: ON  
Alarm Relays:  
Defeated, Alarm 1 at 1000 ppb,  
Alarm 2 at 100 ppb HI, Not  
failsafe, Not latching.  
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4.2  
The Analyzer application  
The Pocket Personal Computer (PPC) is the brains of the analyzer.  
The PPC runs the Analyzer program installed by TAI. For the  
instrument to operate, the program must be launched as instructed in  
section 3.6.  
When the program is launched the main screen will appear as  
shown below.  
Figure 4-1: Main Menu  
The screen shows controls that should be familiar to anyone who has  
used a personal computer.  
Alarm 1. Pressing this button opens a new screen where  
Alarm 1 trigger point and options can be set.  
Alarm 2. Pressing this button opens a new screen where  
Alarm 2 trigger point and options can be set.  
Zero. Pressing this button opens a screen for the zero  
calibration function.  
Span. Pressing this button opens the screen for the span  
calibration function.  
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System. Pressing this button will open a second screen that  
consists of several variables that regulate the internal  
operations of the analyzer.  
Training Video. This buttons launches a video player. At this  
point you could view a short training video regarding BDS  
technology. The presentation will time out and return back to  
the Analyzer application after a period of time.  
Ranges. The list box is used to set the analyzer on a specific  
range as well as set the limits of the ranges.  
Any function can be selected at any time by pressing the  
appropriate button. The order as presented in this manual is appropriate  
for an initial setup.  
Each of these functions is described in greater detail in the  
following procedures.  
4.3  
The System Screen  
Pressing the System button on the main screen will bring the  
System screen.  
The System screen will time out in five minutes and return to the  
main screen. Pressing the Done button will also return you to the main  
screen.  
4.3.1 Communication Information and  
Calibration Parameters  
The first block on the System screen displays information about  
data received, calibration parameters, and data sent to the I/O hardware.  
Received data: 014508900  
Zero Offset: 0  
Span Factor: 38.00  
Amp Gain/Range ID/DAC: 0/0/265  
The first line displays the data received from the I/O PCB. It consists of  
nine digits. The first four digits are the Analog to Digital counts of the BDS  
sensor amplifier. The range of this count is between 0000 and 4095. The  
following four digits are the Analog to Digital counts of the temperature  
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amplifier. The range of this count is the same as the BDS sensor, 0000 to  
4095. The last digit is a status digit—zero indicates the I/O PCB is in normal  
mode. If the I/O PCB receives a remote command to zero or span, it will let  
the PPC program know through this digit.  
Zero Offset line displays the actual Analog to Digital count of the  
electronics plus sensor offset stored in the memory of the PPC. The  
lower the number the better, but a high number does not hinder the  
performance of the sensor very much. One reason for a high count could  
mean that the sensor is still drifting downward and therefore an  
additional zero calibration might be needed to maintain accuracy.  
Span Factor displays a number which is a factor needed to convert  
digital counts to PPB oxygen concentration. This number should be  
between 10 and 40.  
AmpGain/RangeID/DAC displays the command sent to the I/O PCB  
and determines what gain the amplifier should have and what range ID  
contact should open. Both numbers are from 0 to 4. Usually, with default  
ranges, they should be the same but not necessarily.  
DAC is a count number sent to the analog to digital converter of the  
I/O PCB. This sets the output for the concentration 0-1 vdc and 4-20 madc  
outputs. Its range is from 0 to 4095. A large discrepancy between AmpGain  
and RangeID would point to a hardware problem e.g.:  
AmpGain/RangeID/DAC: 0/4/265.  
4.3.2  
Setting Software Parameters: Filter, Gas  
Factor, Tmp. Coeff.  
There are three parameters that are under the control of the user and  
are accessible from the parameter selection box as shown below. These  
are:  
Digital filter—noise reduction  
Gas Factor—compensates for different background gases  
Temperature coefficient—corrects baseline drift due to  
temperature.  
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Select Factor to Adjust  
Tmp. Coeff.  
Filter  
Gas Factor  
Figure 4.2: Parameter Selection Box  
4.3.2.1 THE DIGITAL FILTER  
The Analyzer software performs a digital operation to reduce the  
noise from the BDS sensor and amplifier. This filtering is reduced to  
around 10 ppb. If the signal exceeds 10 ppb, the filter disengages in  
order to track the transient faster. The number approximately  
corresponds to the response time of the filter in minutes from 10 to 90  
%. The range is from 1 to 60 minutes of the 90 % response time. Five  
minutes is the default.  
4.3.2.2 The Gas Factor  
The gas factor coefficient in the BDS 3960 is the ratio of the output  
of the sensor taken in a N2 background over the output of the sensor in  
the new background gas. The output of the sensor depends on the  
mechanics of diffusion. Since the diffusion coefficient of oxygen  
depends on the viscosity of the background gas, according to the laws of  
diffusion, the output of the sensor becomes inversely proportional to the  
viscosity of the background gas.  
The output of the sensor can be predicted by looking up the  
viscosity of the new background gas and compare it to the viscosity of  
N2 at the same temperature. Using values obtained from the a science  
handbook, the following gas factor coefficients for the BDS sensors are  
calculated  
Table 4-1: Gas Factor for Selected Gases  
N2 = 1*  
H2= 1.99  
He= 0.90  
Ar= 0.79  
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*Output normalized by calibrating with a span gas in N2.  
The values in Table 4-1 are theoretical but should give a first  
approximation as to what the output of the sensor will be in the new  
background gas. The BDS 3960 will make further refinements once the  
proper gas factor is input.  
The working range of adjustment is 0.25 to 2.50. This factor will  
divide the output. For example if the factor is set to 2.00, the output of  
the sensor, when read by the PPC application will be divided by two.  
Special consideration on the working range: Changing the gas  
correction factor has an effect on the maximum working range of the  
analyzer, e.g.: if a gas factor of 2.00 is selected the maximum working  
range of the analyzer is 50 ppm. Any reading above this, may saturate  
the amplifier.  
4.3.2.3 TEMPERATURE COEFFICIENT  
The output of the sensor is affected by temperature. There are two  
types of temperature compensation on the BDS 3960. One is the  
compensation to high levels of oxygen, more than 100 ppb. This effect is  
transparent to the user and is handled by the software application on the  
PPC. It requires no input from the user. The second compensation  
involves the baseline drift due to temperature. This value is generally set  
at the factory but can be modified or adjusted by the user. Since the  
sensor is temperature controlled, the default is zero. The following  
discussion is just information on its possibilities.  
The baseline drift temperature coefficient is a number with units of  
ppb/degree centigrade and must be matched to the sensor’s characteristic  
drift over temperature. This coefficient ranges from 0.50 to 1.75 ppb/°C.  
Note: The coefficient is different from sensor to sensor. If the  
sensor is replaced, a new coefficient must be entered. TAI  
can supply this coefficient or it may be determined by the  
user.  
The coefficient can be adjusted between 0.00 and 5.00 using the Up  
and Down buttons on the instrument. To estimate it in the field:  
1. Set the coefficient to zero.  
2. Run the analyzer on “Zero” calibration gas for two weeks or  
until a baseline stability is reached, i.e. the oxygen reading does  
not fluctuate.  
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3. After the sensor has been purged for at least two weeks and the  
baseline is stable, monitor the oxygen reading and ambient  
temperature over a minimum period of 24 hours.  
Take the maximum and minimum oxygen readings, and the  
maximum and minimum temperature readings.  
4. Calculate the coefficient using the relation:  
Coefficient = (O2 max - O2 min) ÷ (Temp max - Temp min  
For example:  
In a 24 hour run:  
O2 max = 3.55 ppb  
)
O2 min = 1.75 ppb  
Temp max = 24.5 degrees C.  
Temp min = 22.1 degrees C.  
Coefficient = (3.55-1.75)ppb ÷ (24.5-22.1) °C = 0.75 ppb/°C.  
This value is currently set to zero, since the sensor is  
temperature controlled and should be left at zero unless qualified  
personnel give instructions to change it.  
4.3.2.4 SET DEFAULTS  
The Set Defaults button will reset all parameters in the software,  
such as calibration, alarm and range settings, Filter, Gas Factor,  
temperature coefficient, etc. to their factory default values. Some of the  
default values are listed below:  
Table 4-2: Parameter Default Values  
Parameter  
Zero Offset  
Span Gas  
SpanFactor  
Default Value  
0
8.00 PPM  
24.42 (Default span factor =  
100000 ppb/ 4095 ADC counts)  
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Filter  
5 minutes  
1.00  
Gas Factor  
Temperature Coef.  
Alarm 1 setpoint  
Alarm 2 setpoint  
0 ppb/degree centigrade  
1000 ppb  
100 ppb  
Pressing the Set Defaults button brings up a confirmation dialog  
box. Press Yes to reset to the defaults or No to keep the current values.  
4.4  
Calibration of the Analyzer  
The analyzer must be calibrated prior to use. For most applications  
where the desired range of measurement is 0 to 10 ppm, or less we  
recommend the analyzer be calibrated using a span gas with a  
concentration between 7.0 to 9.0 ppm oxygen in nitrogen. This will  
require that calibration be performed in the 0-10 ppm analyzer range.  
Before the cell is ready for calibration, it must be purged with  
sample gas to a low oxygen level—preferably below 0.1 ppm. If the  
oxygen content of the sample gas is higher than 0.1 ppm, a zero gas such  
as nitrogen having an oxygen concentration below 0.1 ppm may be  
required.  
4.4.1 Zero Cal  
The BDS Sensor has a zero offset of less than 5 ppb oxygen.  
Normally, the offset slowly decreases during the first 7 to 10 days of  
operation, and is expected to reach a steady value after this time.  
Generally, the value of the zero offset is part of the oxygen reading  
of the sample gas as shown by the analyzer readout. As an example, a  
reading of 5 ppb oxygen may include 0.4 ppm oxygen in the sample gas  
and a 5 ppb zero offset.  
The determination of the zero offset requires the use of oxygen free  
gas to the analyzer. The BDS 3960 has an oxygen scrubber as an  
integral part of its sample system. The software and electronics  
automatically re-route the sample gas through the scrubber to provide  
the sensor with oxygen free gas. Best results as well as prolonged  
scrubber life is attained when the oxygen concentration of the sample  
gas is below 1 ppm oxygen.  
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A zero calibration is not recommended during the first 10 days of  
the operation of the cell.  
The ZERO button on the Main screen is used to enter the zero  
calibration function. Zero calibration can be performed either  
automatically or manually.  
In the automatic mode, an internal timer will purge sensor for five  
minutes before registering the zero offset of the sensor plus electronics.  
As the timer counts down, you can force the analyzer to accept the  
current zero offset using the Accept button. Pressing the Accept button  
anytime during the countdown period forces the analyzer to accept the  
zero offset calibration.  
Pressing Cancel will return the analyzer back to the analyze mode  
without accepting the zero calibration. In this case, the previous zero  
calibration values will remain as the current values.  
4.4.1.1 ZERO FAILURE  
The analyzer checks the output of the cell at the end of the span. If  
the raw output of the cell produces an Analog to Digital converter count  
less than 4000 on amplifier gain 0, the zero will not be accepted. The  
analyzer will use the previous calibration values, and display at the top  
of the main screen:  
ZERO-CALIBRATION  
ERROR  
4.4.2 Span Cal  
The SPAN button on the main screen is used to span calibrate the  
analyzer. Span calibration can be performed automatically or manually.  
In the automatic mode, an internal timer will purge sensor for five  
minutes before taking in the zero offset of the sensor plus electronics.  
Again, the ACCEPT button can be pressed at anytime during the  
countdown period to accept the zero offset calibration.  
Pressing the CANCEL button will return the analyzer to the  
analyze mode without accepting the zero calibration. The previous zero  
calibration will still be in effect.  
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4.4.2.1 SPAN FAILURE  
The analyzer checks the output of the cell at the end of the span. If  
the raw output of the cell is less than 1.5 nA/ppb or more than 13.5  
nA/ppb O2, the span will not be accepted. The analyzer will return to  
the previous calibration values, and display at the top of the main  
screen:  
SPAN-CALIBRATION  
ERROR  
4.5  
The Alarms Function  
The Model BDS 3960 is equipped with 2 fully adjustable  
concentration alarms and a system failure alarm. Each alarm has a relay  
with a set of form “C" contacts rated for 3 amperes resistive load at 250  
VAC. See Figure 3-5 in Chapter 3, Installation and/or the  
Interconnection Diagram included at the back of this manual for relay  
terminal connections.  
The system failure alarm has a fixed configuration as described in  
Chapter 3 Installation.  
The concentration alarms can be configured from the PPC software  
as either high or low alarms by the operator. The alarm modes can be set  
as latching or non-latching, and either failsafe or non-failsafe, or, they  
can be defeated altogether. The setpoints for the alarms are also  
established using this function.  
Depending on your process, you can choose to configure the alarms  
in a number of ways. Consider the following four points:  
1. Which if any of the alarms are to be high alarms and which if  
any are to be low alarms?  
Setting an alarm as HIGH triggers the alarm when the oxygen  
concentration rises above the setpoint. Setting an alarm as LOW  
triggers the alarm when the oxygen concentration falls below  
the setpoint.  
Decide whether you want the alarms to be set as:  
Both high (high and high-high) alarms, or  
One high and one low alarm, or  
Both low (low and low-low) alarms.  
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2. Are either or both of the alarms to be configured as failsafe?  
In failsafe mode, the alarm relay de-energizes in an alarm  
condition. For non-failsafe operation, the relay is energized in  
an alarm condition. You can set either or both of the  
concentration alarms to operate in failsafe or non-failsafe mode.  
3. Are either of the alarms to be latching?  
In latching mode, once the alarm or alarms trigger, they will  
remain in the alarm mode even if process conditions revert back  
to non-alarm conditions. This mode requires an alarm to be  
recognized before it can be reset. In the non-latching mode, the  
alarm status will terminate when process conditions revert to  
non-alarm conditions.  
4. Are either of the alarms to be defeated?  
The defeat alarm mode is incorporated into the alarm circuit so  
that maintenance can be performed under conditions which  
would normally activate the alarms.  
The defeat function can also be used to reset a latched alarm.  
(See procedures, below.)  
Each of the concentration alarms have their own button on Main  
display of the PPC application, ALARM 1 and ALARM 2. Once you  
press on the alarm buttons you will be presented with alarm setup  
screen.  
Five parameters can be changed on the alarm setup screen:  
1. Value of the alarm level—#### ppb (oxygen); value can be set  
from 0 to 100,000 ppb.  
2. Out-of-range direction—High or Low  
3. Latch control—Latching or Non-latching.  
4. On/off Control—Active or Defeated.  
5. Safety Mode—Failsafe or Non-failsafe.  
To reset a latched alarm, go to On/off Control and select defeated.  
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4.6  
The Range Function  
The Range function allows the operator to program up to four  
concentration ranges to correlate with the DC analog outputs. If no  
ranges are defined by the user, the instrument defaults to:  
Range 1 = 0–100 ppb  
Range 2 = 0–1000 ppb  
Range 3 = 0–10000 ppb  
Range 4 = 0–100000 ppb  
The Model BDS 3960 is set at the factory to default to autoranging. In  
this mode, the PPC application automatically responds to concentration  
changes by switching ranges for optimum readout sensitivity. If the current  
range limits are exceeded, the instrument will automatically shift to the next  
higher range. If the concentration falls to below 90% of full scale of the  
next lower range, the instrument will switch to that range. A corresponding  
shift in the DC percent-of-range output, and in the range ID outputs, will be  
noticed.  
The autoranging feature can be overridden so that analog output  
stays on a fixed range regardless of the oxygen concentration detected. If  
the concentration exceeds the upper limit of the range, the DC output  
will saturate at 1 VDC (20 mA at the current output).  
Even if the output is set to a fixed range, the digital readout of the  
concentration is unaffected by the fixed range. It continues to read  
accurately with full precision. See Front Panel description in Chapter 1.  
The automatic fourth range is always 0-100000 ppb (100 ppm) and  
should not be adjusted.  
4.6.1 Setting the Analog Output Ranges  
To set the ranges, click on the list box on the main screen. The  
following options will pop down.  
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Figure 4.3: Range Options List Box  
To Set the ranges to values different than the default, click on ‘Set  
Range’ and the Set Range screen will pop up.  
Set Range 1 Limit  
Upper Limit  
UP  
PPB  
100  
RANGE  
DN  
CANCEL  
OK  
Figure 4.4: Range Setup Screen  
The first screen allows you to set range 1. If you click on the Range  
button, it will take you to the setup of range 2. Click Range again will  
take you to the setup of range 3, then range 4, then back again to range  
1. Note that ranges and alarms are set in ppb units.  
Note: The ranges must sequentially increase from low to high, for  
example, if range 1 is set as 0–100 ppb and range 2 is set  
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as 0–1000 ppb, range 3 cannot be set as 0– 500 ppb since  
it is lower than range 2.  
Note: Refer to Section 4.3.2.2 to find maximum working range.  
4.6.2 Fixed Range Analysis  
The autoranging mode of the instrument can be overridden, forcing  
the analyzer DC outputs to stay in a single predetermined range.  
To switch from autoranging to fixed range analysis, click on the list  
box of the main screen, as shown on figure 4.3, then select on the range  
of interest.  
4.8  
Signal Output  
The standard Model BDS 3960 Oxygen Analyzer is equipped with  
two 0–1 VDC analog output terminals (one concentration and one range  
ID), and two isolated 4–20 mA DC current outputs (one concentration  
and one range ID) accessible from the 50-pin equipment interface  
connector located on the back panel.  
See Rear Panel in Chapter 3, Installation, for illustration and pin  
configuration of the interface connector.  
The signal output for concentration is linear over the currently  
selected analysis range. For example, if the analyzer is set on a range  
that was defined as 0–100 ppb O2, then the output would be as shown in  
Table 4-2.  
Table 4-2: Linear Output for a 0-100 ppm O2 Range  
Voltage Signal  
Current Signal  
ppb O2  
0
Output (VDC)  
Output (mA DC)  
0.0  
0.1  
0.2  
0.3  
0.4  
0.5  
4.0  
5.6  
10  
20  
7.2  
30  
8.8  
40  
10.4  
12.0  
50  
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60  
70  
0.6  
0.7  
0.8  
0.9  
1.0  
13.6  
15.2  
16.8  
18.4  
20.0  
80  
90  
100  
The analog output signal has a voltage which depends on the  
oxygen concentration AND the currently activated analysis range. To  
relate the signal output to the actual concentration, it is necessary to  
know what range the instrument is currently on, especially when the  
analyzer is in the autoranging mode.  
To provide an indication of the range, a second pair of analog  
output terminals are used. They generate a steady preset voltage (or  
current when using the current outputs) to represent a particular range.  
Table 4-3 gives the range ID output for each analysis range.  
Table 4-3: Range ID Output  
Range  
Range 1  
Range 2  
Range 3  
Range 4  
Voltage (V)  
0.25  
Current (mA)  
8
0.50  
12  
16  
20  
0.75  
1.00  
4.9  
Front  
Switching The Program Back To The  
There are times that the Analyzer program may drop out of sight  
from the front of the screen even though it is still running. If Analyzer  
program icon is tapped to run the program, an error message will be  
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displayed. This is because windows CE® does not allow two instances  
of the same program.  
If this occurs, tap on the blue the corner of the blue bar (blue bar  
appears either at the top of the screen or at the bottom, depending on  
which application is at the front), next to the windows logo, to bring up  
the pop up menu.  
- Tap on Settings  
- On the Settings form, tap on the System tab  
- Tap on the Memory icon  
- Tap on the Running Programs tab  
- Tap ot “TET-AI PPB OXYGEN ANALYER” on the program  
lists to select the Analyzer program  
- Tap the Activate button. Now the Analyzer program should be at  
the front.  
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Maintenance  
5.1 Routine Maintenance  
Aside from normal cleaning and checking for leaks at the gas  
connections, routine maintenance is limited to refilling sensor with  
deionized water, replace burned fuses, replace backup batteries for PPC,  
and recalibration. For recalibration, see Section 4.4 Calibration.  
WARNING: SEE WARNINGS ON THE TITLE PAGE OF THIS  
MANUAL.  
5.2  
Adding Water to the BDS Sensor  
When running dry gas through the sensor, water is extracted from  
the electrolyte. Therefore, the electrolyte level should be checked  
periodically. When the electrolyte level is low, only de-ionized water or  
distilled water should be added into the sensor. It typically takes about  
four months to dry the electrolyte from the MAX line to the MIN line  
when the sensor is operated on a bone dry gas line.  
It is not necessary to turn off the power to the analyzer while  
adding water, but care should be taken that no water is splashed outside  
the sensor. Spilling water on the PC board could cause serious damage  
to the analyzer and electric shock to the personal.  
Unscrew and take the sensor cap off. Use the wash bottle provided  
to squeeze de-ionized water into the sensor, as shown in Figure 5.1. It is  
a good practice that water is added before reaching the MIN line.  
Reinstall the cap after adding water.  
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Figure 5.1 Adding Water into the BDS sensor  
WARNING: THE SENSOR USED IN THE MODEL BDS 3960  
OXYGEN ANALYZER USES ELECTROLYTE WHICH  
CONTAINS POTASSIUM HYDROXIDE, THAT CAN BE  
HARMFUL IF TOUCHED, SWALLOWED, OR  
INHALED. AVOID CONTACT WITH ANY FLUID OR  
POWDER IN OR AROUND THE UNIT. WHAT MAY  
APPEAR TO BE PLAIN WATER COULD BE THE  
ELECTROLYTE. IN CASE OF EYE CONTACT,  
IMMEDIATELY FLUSH EYES WITH WATER FOR AT  
LEAST 15 MINUTES. CALL PHYSICIAN. (SEE  
APPENDIX, MATERIAL SAFETY DATA SHEET.)  
5.3  
Fuse Replacement  
1. Place small screwdriver in notch, and pry cover off, as shown in  
Figure 5-2. Remove fuse holder.  
2. Replace fuses. Use 2A 250 VAC 5x20 mm slow-blow. Install  
one at each side of fuse holder  
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Figure 5-2: Removing Fuse Block from Housing  
5.4  
Battery Backup Replacement  
The software application running on the PPC is mantained when  
power is removed from the analyzer by a single 3 volt lithium battery. If  
the unit is powered down and the battery power is low, you run the risk  
of losing the program. To prevent this from happening, replace the  
backup battery as often as six months. Use a CR2032 or DL2032 for  
replacement.  
Note: Make sure that the main battery of the PPC is charged  
when you change the backup battery or you will the  
software application. If the software application is lost for  
any reason, use the installation floppy disk as instructed in  
section 5.5.  
1. Power Analyzer down.  
2. Loosen the thumb screws of the front panel and slide the drawer  
assembly out.  
3. Remove the two screws on the back of the front panel that hold  
the PPC in place, then remove the PPC.  
4. Slide the switch on the back of the PPC to Backup. Open the  
battery compartment and remove the old battery.  
5. Install a new battery. Make sure that the ‘+’ side is on top facing  
out.  
6. Replace the battery cover and move the switch to lock position.  
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5.5 Reinstalling Application software to PPC.  
If the applications software on the PPC becomes corrupt or is lost,  
it can be restored by Downloading the Analyzer program and  
components. Before installing the software, you must have a software  
version of ActiveSync® on a separate PC computer running Windows  
95 or later operating system as well as a serial communication cable or  
cradle TAI P/N CP2237. ActiveSync® is a property of Microsoft Corp.  
and can be downloaded from their website. The Analyzer program and  
its components can be send via email upon request. Please have serial  
number of analyzer, it will be requested.  
1. Connect the PPC to the serial communication cable or cradle.  
2. Launch ActiveSync.  
3. Open ActiveSync Explorer  
4. Insert the backup floppy in the disk drive of the PC computer and  
open the Windows Explorer.  
5. Locate the file vbceutil.dll and copy it to the windows directory of  
the PPC, file size is 77Kb  
6. Similarly, copy regsvrce program for the PPC 300 to the windows  
directory on the PPC, file size is 7.50kb (this is the version for  
target\mips).  
7. Run CD1\setup.exe to install the analyzer program  
8. Move Teledyne_log.bmp to \Analyzer directory on the PPC.  
9. Register vbceutil.dll on the PPC as follows:  
Click start_Programs_explorer  
Click show_My Device  
Double click on the windows folder  
Find regsvrce program and double click to run;  
Type path:  
c:\windows\vbceutil.dll  
then press OK button  
Double click on regsvrce program icon to get the message  
that the registration was successful. If it was not successful,  
repeat the last two steps.  
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10. Disconnect the serial cable and run the Analyzer program from the  
Start pull down menu to check for successful installation.  
5.5  
Major Internal Components  
The Sensor is accessed by loosening the thumbscrew on the front  
panel and sliding it out, as described earlier. Other internal components can  
be accessed the same way. The gas piping is illustrated in Figure 2-3, and  
the major electronic component locations are described in Chapter 2.  
WARNING: SEE WARNINGS ON THE TITLE PAGE OF THIS  
MANUAL.  
The BDS 3960 contains the following major components:  
Analysis Section  
Sensor with stainless steel wetted parts  
Sample system  
Power Supply PCB  
Microprocessor base I/O board with amplifier daughter board  
LED display PCB  
Palm Portable Computer with Windows CE  
See the drawings in the Drawings section in back of this manual for  
details.  
5.6  
Cleaning  
If the instrument is unmounted at time of cleaning, disconnect the  
instrument from the power source. Close the front-panel access drawer.  
Clean outside surfaces with a soft cloth dampened slightly with plain  
clean water. Do not use any harsh solvents such as paint thinner or  
benzene.  
DO NOT wipe front panel while the instrument is controlling your  
process.  
5.7  
Troubleshooting  
Symptoms  
Possible causes and Solutions  
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Read higher than expected (1), (2), (3)  
Read lower than expected  
Read negative  
(2), (3)  
(3), (4)  
(3), (5)  
(5)  
Noise signal  
Slow response  
Causes and solution keys:  
(1) Gas leak: Make sure to use new VCR gaskets, high quality  
valves and gas regulator for the sampling system. Tighten each  
connection.  
(2) Improper gas flow rate: adjust the inlet pressure to obtain 0.5 –  
1 SLPM flow rate.  
(3) Improper calibration of the analyzer: Press the SYSTEM  
button on Main menu screen of the PPC to bring the System  
screen. Then press the “Set default” button. This will return the  
analyzer to its defaults settings in calibration and zero values.  
Recalibrate the analyzer with a high quality standard gas if it is  
necessary. Be warned this will set defaults to ranges and alarms  
settings as well.  
(4) Just after adding water: The analyzer will recover by itself.  
(5) Gas entered and is trapped in the sensor: This could happen if  
the sensor is filled with the electrolyte improperly, or the sensor  
is pressurized because of a clogged vent. To remedy this  
situation, uninstall the sensor and take off the cap carefully, then  
apply a vacuum degas process as shown in the Figure 5-4.  
Degassing in a 28 inch mercury vacuum for 5 minutes is  
sufficient to remove the gas bubbles. Reinstall the sensor into the  
analyzer.  
Note: A low cost vacuum degas kit (TAI P/N B72098) is available  
from Teledyne Analytical Instruments.  
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Figure 5-3: Vacuum Degassing for the BDS Oxygen Sensor  
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Appendix  
BDS 3960  
Appendix  
A-1  
Specifications  
Packaging: General Purpose  
• Flush panel mount (Standard).  
Sensor: Teledyne BDS Sensor, patent pending.  
Sample System: All wetted parts of 316 stainless steel with  
built-in in pressure regulator, oxygen  
scrubber and calibration valves.  
90 % Response Time: Less than 90 seconds at 25 °C (77 °F) on  
10, and 100 ppm range. 90 seconds on  
1000ppb range.  
Software programmable response in 100  
ppb range from 1 minute to 60 minutes.  
Default is 5 minutes response time.  
Ranges: Three user definable ranges from  
0–100 ppb to 0–100 ppm, plus over range  
of 0-100 ppm.  
Autoranging with range ID output.  
Alarms: One system-failure alarm contact to detect  
power failure or sensor-zero and span  
failure.  
Two adjustable concentration threshold  
alarm contacts with fully programmable  
setpoints.  
Displays: 5 digit LED display and Backlit LCD  
display from PPC  
Power: Universal power supply 100-125 VAC, at  
50/60 Hz. 200-240 VAC optional  
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Oxygen Analyzer  
Appendix  
Operating Temperature: 5-40 °C  
Accuracy: 2% of full scale for all ranges at constant  
temperature.  
All accuracy specifications are contingent  
upon the completion of zero and span  
calibration.  
All accuracy is established at constant  
pressure and equilibrium has been  
established.  
Analog outputs: 0-1 VDC percent-of-range,  
0-1 VDC range ID.  
4-20 mA DC (isolated) percent-of-range,  
4-20 mA DC (isolated) range ID.  
Dimensions: 19 cm high, 24.9 cm wide, 31 cm deep  
(6.96 in high, 8.7 in wide, 12.1 in deep).  
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Appendix  
BDS 3960  
A-2  
Recommended 2-Year Spare Parts List  
Qty.  
Part Number Description  
1
1
1
1
2
C65507B  
C72914A  
C72000A  
B71997A  
F1296  
Back Panel Board  
Front Panel Board  
Preamplifier Board (Instruction)  
Main Computer Board  
Fuse, 2A, 250V 5x20mm (European)  
Slow Blow  
1
CP1798  
CP1799  
B597  
50 pin D-sub interface connector  
Pins for CP1798 connector  
125ml wash bottle for DI water  
125ml electrolyte bottle  
Pipet  
50  
1
1
B598  
1
P1076  
1
B72098  
CP2237  
C58750  
BDS sensor recovery kit  
PDA cradle  
1
1
Oxygen Scrubber  
Note: Orders for replacement parts should include the part  
number (if available) and the model and serial number of  
the instrument for which the parts are intended.  
Orders should be sent to:  
TELEDYNE Analytical Instruments  
16830 Chestnut Street  
City of Industry, CA 91749-1580  
Phone (626) 934-1500, Fax (626) 961-2538  
or your local representative.  
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Oxygen Analyzer  
Appendix  
A-3  
Drawing List  
D-73299 Outline Diagram  
A-4  
19-inch Relay Rack Panel Mount  
Figure A-1: Single 19" Rack Mount (dimensions in mm)  
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Appendix  
BDS 3960  
A-5  
Application notes  
Pressure and flow recommendations:  
3960 series analyzers require reasonably regulated sample  
pressures. While the 3960 analyzers are not sensitive to variations of  
incoming pressure (provided they are properly vented to atmospheric  
pressure), the pressure must be maintained so as to provide a useable  
flow rate through the analyzer. Any line attached to sample vent should  
be 1/4" or larger in diameter.  
Flow rate recommendations:  
A usable flow rate for a 3960 series analyzer is one which can be  
measured on the flowmeter. This is basically 0.5 - 1.0 SLPM. The  
optimum flow rate is 1 SLPM (mid scale). Note: response time is  
dependent on flow rate, a low flow rate will result in slow response to  
O2 changes in the sample stream. The span flow rate should be the  
approximately same as the sample flow rate.  
Cell pressure concerns:  
The sensors used in 3960 series analyzers are optimized to  
function at atmospheric pressure.  
Bypass:  
To improve the system response, a bypass can be added to  
increase the sample flow rate to the analyzer by a factor of ten. A by-  
pass provides a sample flow path around the analyzer of 2 - 18 SCFH.  
typically.  
Conversons:  
1 PSI  
=
2.04 INCHES OF MERCURY (in. Hg.)  
0.476 SLPM  
1 SCFH =  
Note: The MSDS on this material is available upon request  
through the Teledyne Environmental, Health and Safety  
Coordinator. Contact at (626) 934-1592  
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Oxygen Analyzer  
Appendix  
Material Safety Data Sheet  
Section I - Product Identification  
Micro-fuel Cells  
Product Name:  
Mini-Micro-fuel Cells  
Super Cell, all classes except T-5F  
Electrochemical Oxygen Sensors, all classes  
Manufacturer: Teledyne Electronic Technologies  
Analytical Instruments  
Address: 16380 Chestnut Street,  
City of Industry, CA 91749  
(626) 961-9221  
Phone:  
Technical Support: (626) 934-1673  
Environment, Health and (626) 934-1592  
Safety:  
11/23/98  
Date Prepared:  
Section II - Physical and Chemical Data  
Chemical and Common  
Potassium Hydroxide (KOH), 15% (w/v)  
Lead (Pb), pure  
Names:  
CAS Number:  
KOH 1310-58-3  
Pb 7439-92-1  
KOH (15% w/v)  
-10 to 0 °C  
100 to 115 °C  
1.09 @ 20 °C  
>14  
Pb (pure)  
328 °C  
1744 °C  
11.34  
Melting Point/Range:  
Boiling Point/Range:  
Specific Gravity:  
pH:  
N/A  
Solubility in Water:  
Percent Volatiles by Vol.:  
Appearance and Odor:  
Completely soluble  
None  
Insoluble  
N/A  
Colorless, odorless  
solution  
Grey metal,  
odorless  
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Appendix  
BDS 3960  
Section III -Physical Hazards  
Potential for fire and explosion: The electrolyte in the Micro-fuel Cells is not  
flammable. There are no fire or explosion hazards associated with Micro-fuel  
Cells.  
Potential for reactivity: The sensors are stable under normal conditions of  
use. Avoid contact between the sensor electrolyte and strong acids.  
Section IV - Health Hazard Data  
Ingestion, eye/skin contact  
Primary route of entry:  
Exposure limits: OSHA PEL: 0.05 mg./cu.m. (Pb)  
ACGIH TLV: 2 mg/ cu.m. (KOH)  
Effects of overexposure  
Ingestion: The electrolyte could be harmful or fatal if  
swallowed.  
Oral LD50 (RAT) = 3650 mg/kg  
Eye: The electrolyte is corrosive; eye contact could  
result in permanent loss of vision.  
Dermal: The electrolyte is corrosive; skin contact could  
result in a chemical burn.  
Inhalation: Liquid inhalation is unlikely.  
Contact with skin or eyes will cause a burning  
sensation and/or feel soapy or slippery to  
touch.  
Signs/symptoms of exposure:  
Medical conditions  
aggravated by exposure: None  
NTP Annual Report on Carcinogens: Not  
Carcinogenicity:  
listed  
LARC Monographs: Not listed  
OSHA: Not listed  
Other health hazards: Lead is listed as a chemical known to the State  
of California to cause birth defects or other  
reproductive harm.  
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Oxygen Analyzer  
Appendix  
Section V - Emergency and First Aid Procedures  
Eye Contact: Flush eyes with water for at least 15 minutes  
and get immediate medical attention.  
Skin Contact: Wash affected area with plenty of water and  
remove contaminated clothing. If burning  
persists, seek medical attention.  
Give plenty of cold water. Do not induce  
vomiting. Seek medical attention. Do not  
administer liquids to an unconscious person.  
Ingestion:  
Inhalation: Liquid inhalation is unlikely.  
Section VI - Handling Information  
NOTE: The oxygen sensors are sealed, and under normal circumstances, the  
contents of the sensors do not present a health hazard. The following  
information is given as a guide in the event that a cell leaks.  
Rubber gloves, chemical splash goggles.  
Protective clothing:  
Clean-up procedures: Wipe down the area several times with a wet  
paper towel. Use a fresh towel each time.  
Protective measures Before opening the bag containing the sensor  
during cell replacement: cell, check the sensor cell for leakage. If the  
sensor cell leaks, do not open the bag. If there  
is liquid around the cell while in the  
instrument, put on gloves and eye protection  
before removing the cell.  
Disposal: Should be in accordance with all applicable  
state, local and federal regulations.  
NOTE: The above information is derived from the MSDS provided by the  
manufacturer. The information is believed to be correct but does not  
purport to be all inclusive and shall be used only as a guide.  
Teledyne Analytical Instruments shall not be held liable for any  
damage resulting from handling or from contact with the above  
product.  
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Appendix  
BDS 3960  
Index  
access door, 16  
stability, 24  
accuracy, 67  
BDS sensor output  
output correction, 23  
bipotentiostat. See BDS sensor  
block diagram, 26, 28  
bypass, 33, 70  
ActiveSync, 61  
adding electrolyte, 39  
adding water, 59  
address, 68, See company address  
Ag/Ag2O electrode, 19  
air saturation, 22  
alarm, 51, 66  
calibration, 49  
contact, 37  
relay contact, 38  
remote control, 36  
calibration contact, 16  
calibration gas  
concentration, 14, 16  
failure, 14, 51  
high, 36  
low, 36  
connection, 25  
relay, 35, 51  
relay contact pins, 36  
resetting, 52  
carbon. See reticulated vitreous carbon  
caution sign, iv  
cleaning, 62  
system, 36  
threshold, 36  
ALARMS, 14  
combustible gas warning, xii  
company address. See company  
address  
amplifier saturation, 47  
analog to digital converter, 26  
Analyze button, 43  
applications, 13  
auto cal, 45  
configuring the analyzer, 42  
copyright, ii  
counter electrode, 18  
current  
background, 19  
automatic span mode, 50  
autoranging, 14, 53  
background gas, 23  
BDS sensor, 18, 66  
acid gas exposure, 24  
advantage of, 20  
cross section, 20  
current, 26  
signal, 19  
current to voltage amplifier, 26  
damage, 30  
default, 53  
default values, 42  
defeated (relay out), 35  
de-ionized water, 58  
detection limit, 19  
diffusion barrier, 19, 20  
digital input  
damage, 32  
filling, 39  
maintenance, 24  
output, 21, 22, 23, 32  
span, 37  
zero, 37  
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Oxygen Analyzer  
Index  
digital to analog converter, 26  
dimensions, 67, 69  
display, 26, 66  
model information, iii  
motherboard, 26  
mounting, 30  
dissolved oxygen, 20  
door. See access door  
door clearance, 31  
drawer, 14  
drawings, 69  
drift, 25  
electrochemical cell, 19  
electrochemical device, 18  
electrochemical reaction, 19  
electrode, 18  
electrolyte, 19, 20, 25, 30, 32, 39, 59  
electrolyte level, 25  
electronic block diagram. See block  
diagram  
moving contact, 36  
MSDS, 71  
negative reading, 25  
nonfailsafe, 35  
nonlatching, 35  
normally closed, 35, 36  
normally open, 35, 36  
OH-, 20  
operational amplifier, 19  
operational theory, 18  
outlet, 25, 33  
output, 21, 34  
analog, 14, 16, 55, 67  
connections, 35  
current, 35  
electronics, 18  
equipment interface connector, 34  
estimating temperature coefficient, 47  
exhaust, 33  
linear, 55  
range, 14  
range ID, 34, 56  
voltage, 34  
failsafe, 35  
features, 13  
output signal pins, 34  
override, 14  
feedback control loop, 19  
fixed range, 53, See range  
flow diagram, 25  
flowmeter, 15, 25  
calibration, 23  
flowrate, 21, 32, 70  
form C relay contacts, 35  
front panel, 14, 31  
fuse, 60  
oxygen level, 19  
oxygen standard, 23  
panel mount, 14  
platinum wire, 19  
polarization, 19  
potential reference, 21  
potentiostat, 20  
power, 16, 26  
fuse block, 34  
fuse installation, 34  
gas factor, 23  
power cord, 34  
power supply, 66  
pressure, 22, 32, 70  
excessive, 22  
gas inlet, 16, 20  
gas outlet, 16, 20  
inlet, 25  
pressure regulator. See regulator  
purge, 49  
input  
digital, 16, 36  
input/output, 26  
purge-down, 22  
rack mount, 14, 69  
RAM, 13, 26  
installation, 30  
range, 66  
KOH, 19, 25, 39  
latching, 35  
default, 53  
fixed, 55  
LED, 15  
setting, 53  
maintenance, 58  
manuals, additional, v  
meter, 15  
microcontroller, 26  
microprocessor, 13  
Range, 53  
range ID, 16, 38  
rear panel, 16, 32  
recovery time, 22  
reduction equation, 19  
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Appendix  
BDS 3960  
reference electrode, 18, 21  
refilling the sensor, 39  
regulator, 32  
remote calibration connection, 37  
remote calibration protocol, 37  
remote probe, 16  
failure, 50, 51  
span gas  
concentration, 49  
spare parts listing, 68  
specifications, 66  
subsystem, 18  
response time, 33, 66  
reticulated vitreous carbon, 20  
RFI, 14  
swagelock fitting, 25  
SYSTEM, 14  
Teledyne address, 68  
ROM, 13, 26  
temperature coefficient, 22  
testing the system, 40  
threshold alarm. See alarm  
troubleshooting, 62  
universal power source, 16  
universal power supply, 26, 34, 66  
vacuum degas kit, 63  
VCR fitting, 25, 32  
vent, 22  
safety information, iv  
sample flow. See flowrate  
sample system, 18, 22, 25  
second stage amplifier, 26  
self-diagnostic test, 60  
sensing electrode, 20  
sensor  
output, 21  
serial number, iii  
warning sign, iv  
signal, 19  
warranty, ii  
signal output  
water addition, 24  
web address, 21, 68  
website address, v  
working electrode, 18, 20  
ZERO, 14  
concentration, 27  
signal processing, 18, 26  
software reinstallation, 61  
solenoid valve  
external, 16  
ZERO, 50  
SPAN, 14  
SPAN, 50  
span calibration, 50  
zero calibration, 50  
automatic mode, 50  
zero offset, 49  
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