Sanyo Camera Accessories UR18650A User Guide

Product name: Lithium Ion Battery Cell  
Reference number: SDS-IBT-00010  
Establishment / Revision: Dec.1 2008  
Safety data sheet for chemical products (SDS)  
1. PRODUCT AND COMPANY IDENTIFICATION  
žProduct name: Lithium Ion Battery Cell  
žProduct code: Cylindrical type cell  
UR18650U, UR18650E, UR18650A  
žCompany name:  
Sanyo Electric Co., Ltd. Mobile Energy Company  
222-1 , Kaminaizen, Sumoto City, Hyogo, Japan  
žAddress:  
žTelephone number: +81-799-24-4111  
žFax number: +81-799-24-4121  
žEmergency telephone number: [Weekday] +81-799-23-3942  
[Night and holiday] +81-799-24-4131  
2. COMPOSITION / INFORMATION ON INGREDIENTS  
žSubstance or preparation: Preparation  
žInformation about the chemical nature of product:  
Common chemical name /  
General name  
CAS number  
Concentration /  
Concentration range  
20-40%  
Classification and  
hazard labeling  
-
Lithium metal oxidate  
(Li(Mn-Co-Ni)O2)  
Iron  
-
7439-89-6  
7429-90-5  
15-25%  
2-6%  
-
-
Aluminum  
Graphite  
(Natural graphite)  
(Artificial graphite)  
Copper  
7782-42-5  
7740-44-0  
7440-50-8  
10-20%  
5-15%  
-
Sensitization of the skin  
group No.2  
Inflammable liquid  
Organic electrolyte  
-
10-20%  
3. HAZARDS IDENTIFICATION  
For the battery cell, chemical materials are stored in a hermetically sealed metal case, designed to withstand  
temperatures and pressures encountered during normal use. As a result, during normal use, there is no  
physical danger of ignition or explosion and chemical danger of hazardous materials' leakage.  
However, if exposed to a fire, added mechanical shocks, decomposed, added electric stress by miss-use,  
the gas release vent will be operated. The battery cell case will be breached at the extreme, hazardous  
materials may be released.  
Moreover, if heated strongly by the surrounding fire, acrid gas may be emitted.  
žMost important hazard and effects  
Human health effects:  
Inhalation: The steam of the electrolyte has an anesthesia action and stimulates a respiratory tract.  
Skin contact: The steam of the electrolyte stimulates a skin. The electrolyte skin contact causes a  
sore and stimulation on the skin.  
Eye contact: The steam of the electrolyte stimulates eyes. The electrolyte eye contact causes a sore  
and stimulation on the eye. Especially, substance that causes a strong inflammation of the eyes is  
contained.  
Environmental effects: Since a battery cell remains in the environment, do not throw out it into the  
environment.  
žSpecific hazards:  
If the electrolyte contacts with water, it will generate detrimental hydrogen fluoride.  
Since the leaked electrolyte is inflammable liquid, do not bring close to fire.  
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Product name: Lithium Ion Battery Cell  
Reference number: SDS-IBT-00010  
Establishment / Revision: Dec.1 2008  
8. EXPOSURE CONTROLS / PERSONAL PROTECTION  
žEngineering measures:  
No engineering measure is necessary during normal use. In case of internal cell materials' leakage,  
operate the local exhaust or improve ventilation.  
žControl parameters  
Common chemical name /  
General name  
ACGIH (2002)  
TLV-TWA  
0.02mg/m3 (as cobalt)  
BEI  
-
Lithium metal oxidate  
(Li(Mn-Co-Ni)O2)  
Aluminum  
10mg/m3 (metal coarse particulate)  
5mg/m3 (inflammable powder)  
5mg/m3 (weld fume)  
2mg/m3  
-
Carbon  
Copper  
(Natural graphite)  
(Artificial graphite)  
-
-
-
(inhalant coarse particulate)  
0.2mg/m3 (fume)  
1.0mg/m3 (a coarse particulate, Mist)  
-
Organic electrolyte  
ACGIH: American Conference of Governmental Industrial Hygienists, Inc.  
TLV-TWA: Threshold Limit Value-Time Weighted Average concentration  
BEI: Biological Exposure Indices  
žPersonal protective equipment  
Respiratory protection: Respirator with air cylinder, dust mask  
Hand protection: Protective gloves  
Eye protection: Goggle or protective glasses designed to protect against liquid splashes  
Skin and body protection: Working clothes with long sleeve and long trousers  
9. PHYSICAL AND CHEMICAL PROPERTIES  
žAppearance  
Physical state: Solid  
Form: Cylindrical  
Color: Metallic color (without tube)  
Odor: No odor  
žpH: NA  
žSpecific temperatures/temperature ranges at which changes in physical state occur:  
There is no useful information for the product as a mixture.  
žFlash point: NA  
žExplosion properties: NA  
žDensity: NA  
žSolubility ,with indication of the solvent(s): Insoluble in water  
10. STABILITY AND REACTIVITY  
žStability: Stable under normal use  
žHazardous reactions occurring under specific conditions  
žConditions to avoid: When a battery cell is exposed to an external short-circuit, crushes, deformation,  
high temperature above 100 degree C, it will be the cause of heat generation and ignition. Direct  
sunlight and high humidity.  
žMaterials to avoid: Conductive materials, water, seawater, strong oxidizers and strong acids.  
žHazardous decomposition products: Acrid or harmful gas is emitted during fire.  
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Product name: Lithium Ion Battery Cell Reference number: SDS-IBT-00010  
Establishment / Revision: Dec.1 2008  
11. TOXICOLOGICAL INFORMATION  
There is no available data on the product itself. The information of the internal cell materials is as follows.  
Lithium metal oxidate –Li(Mn-Co-Ni)O2  
žAcute toxicity: No applicable data.  
Reference cobalt: LDLo, oral - Guinea pig 20mg/kg  
manganese: LD50, oral - Guinea pig 9000mg/kg  
nickel: LDLo, oral - Guinea pig 5mg/kg  
žLocal effects: Unknown.  
žSensitization:  
The nervous system of respiratory organs may be stimulated sensitively.  
žChronic toxicity/Long term toxicity:  
By the long-term inhalation of coarse particulate or vapor of cobalt, it is possible to cause the serious  
respiratory-organs disease. Skin reaction or a lung disease for allergic or hypersensitive person may be  
caused.  
By the long-term or repetitive inhalation of coarse particulate of Manganese Oxide (MnO2), lungs and  
nervous system may be affected; bronchitis, pneumonia, nerve disease or nerve mental disorder  
(manganese poisoning) may be caused.  
Nickel Compounds belong to the 1st group of the carcinogen in the IARC category (substance which  
has carcinogenic to man).  
žSkin causticity: Although it is very rare, the rash of the skin and allergic erythema may result.  
Aluminum  
žLocal effects: Aluminum itself has no toxicity. When it goes into a wound, dermatitis may be caused.  
žChronic toxicity/Long term toxicity: By the long-term inhalation of coarse particulate or fume, it is possible  
to cause a lung damage (aluminum lungs).  
Graphite  
žAcute toxicity: Unknown.  
žLocal effects: When it goes into one’s eyes, it stimulates one’s eyes; conjunctivitis, thickening of corneal  
epithelium or edematous inflammation palpebra may be caused.  
žChronic toxicity/Long term toxicity:  
Since the long-term inhalation of high levels of graphite coarse particulate may become a cause of a  
lung disease or a tracheal disease.  
žCarcinogenicity:  
Graphite is not recognized as a cause of cancer by research organizations and natural toxic substance  
research organizations of cancer.  
Copper  
žAcute toxicity:  
60-100mg sized coarse particulate causes a gastrointestinal disturbance with nausea and inflammation.  
TDLo, hypodermic - Rabbit 375mg/kg  
žLocal effects:  
Coarse particulate stimulates a nose and a tracheal.  
When it goes into one’s eyes, the symptom of the reddening and the pain is caused.  
žSensitization: Sensitization of the skin may be caused by long-term or repetitive contact.  
žReproductive effects: TDLo, oral - Rat 152mg/kg  
Organic Electrolyte  
žAcute toxicity:  
LD50, oral - Rat 2,000mg/kg or more  
žLocal effects: Unknown.  
žSkin irritation study: Rabbit - Mild  
žeye irritation study: Rabbit - Very severe  
12. ECOLOGICAL INFORMATION  
žPersistence/degradability:  
Since a battery cell and the internal materials remain in the environment, do not bury or throw out into  
the environment.  
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Product name: Lithium Ion Battery Cell  
13. DISPOSAL CONSIDERATIONS  
Reference number: SDS-IBT-00010  
Establishment / Revision: Dec.1 2008  
žRecommended methods for safe and environmentally preferred disposal:  
Product (waste from residues)  
Do not throw out a used battery cell. Recycle it through the recycling company.  
Contaminated packaging  
Neither a container nor packing is contaminated during normal use. When internal materials leaked  
from a battery cell contaminates, dispose as industrial wastes subject to special control.  
14. TRANSPORT INFORMATION  
In the case of transportation, avoid exposure to high temperature and prevent the formation of any  
condensation. Take in a cargo of them without falling, dropping and breakage. Prevent collapse of cargo piles  
and wet by rain. The container must be handled carefully. Do not give shocks that result in a mark of hitting on  
a cell. Please refer to Section 7-HANDLING AND STORAGE also.  
žUN classification: However this product's shipping name is "Lithium ion batteries" (or "Lithium ion Batteries  
packed with equipment" or "Lithium ion Batteries contained in equipment"), it is not recognized as  
"DANGEROUS GOODS" when its transport condition accords with “packing instruction 965 part 1 of IATA-  
DGR" (or "packing instruction 966 part 1" or "packing instruction 967 part 1") or "special provision 188 of  
IMO-IMDG Code".  
15. REGULATORY INFORMATION  
žRegulations specifically applicable to the product:  
IMO-IMDG Code (sea transportation)  
IATA-DGR (air transportation)  
US Department of Transportation 49 Code of Federal Regulations [USA]  
Wastes Disposal and Public Cleaning Law [Japan]  
Law for Promotion of Effective Utilization of resources [Japan]  
16. OTHER INFORMATION  
žThe information contained in this Safety data sheet is based on the present state of knowledge and  
current legislation.  
žThis safety data sheet provides guidance on health, safety and environmental aspects of the product and  
should not be construed as any guarantee of technical performance or suitability for particular  
applications.  
žReference  
Chemical substances information: Japan Advanced Information center of Safety and Health  
International Chemical Safety Cards (ICSCs): International Occupational Safety and Health Information  
Centre (CIS)  
2002 TLVs and BEIs: American Conference of Governmental Industrial Hygienists (ACGIH)  
Dangerous Goods Regulations - 50th Edition Effective 1 January 2009: International Air Transport  
Association (IATA)  
IMDG Code - 2008 Edition: International Maritime Organization (IMO)  
RTECS (CD-ROM)  
MSDS of raw materials prepared by the manufactures  
First edition:  
Prepared and approved by  
Sanyo Electric Co., Ltd.  
Dec. 01 2003  
Mobile Energy Company  
Battery System Development Management Department  
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