Kodak 1078419 User Manual

Material Safety Data Sheet  
Revision Date: 10/08/2007  
000000023093/Version: 1.2  
Print Date: 02/13/2009  
Page: 1/7  
1. Identification of the substance/preparation and of the company/undertaking  
Product name: KODAK Alkaline Battery KAA, KAA-P  
Product code: 1078419  
Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York 14650; KODAK  
CANADA INC., 6 Monogram Place Suite 200 Toronto, Ontario M9R 0A1  
For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA)  
For other information or to request an MSDS, call (800) 242-2424.  
Synonyms: None.  
Product Use: Battery, For consumer and industrial use.  
2. Hazards identification  
CONTAINS: Manganese dioxide (1313-13-9), Zinc (7440-66-6), Potassium hydroxide (1310-58-3),  
Graphite (7782-42-5)  
WARNING!  
MAY FLAME OR LEAK IF OPENED, SHORT CIRCUITED, RECHARGED, CONNECTED  
IMPROPERLY, OR EXPOSED TO FIRE OR HIGH TEMPERATURES.  
HARMFUL IF SWALLOWED  
VAPORS/FUMES FROM DAMAGED BATTERIES MAY CAUSE RESPIRATORY TRACT IRRITATION  
DAMAGED BATTERIES MAY CAUSE SKIN AND EYE BURNS  
3. Composition/information on ingredients  
Weight %  
30 - 40  
10 - 20  
5 - 10  
Components - (CAS-No.)  
Manganese dioxide (1313-13-9)  
Zinc (7440-66-6)  
Potassium hydroxide (1310-58-3)  
Graphite (7782-42-5)  
1 - 5  
Weight % listed is based on approximate percent of the average weight of the battery (38 grams).  
The components in this section may only represent a hazard if the integrity of the battery is compromised.  
4. First aid measures  
The routine handling and use of intact, non-damaged batteries is not expected to result in situations that  
require first-aid measures. If battery is damaged due to opening, cutting, crushing, overheating, improper  
installation, exposure to fire or high temperatures, or recharging, battery contents may be released.  
Inhalation: If vapours or fumes from vented or leaking battery are irritating to respiratory tract, move to  
fresh air. Get medical attention if symptoms occur.  
Material Safety Data Sheet  
Revision Date: 10/08/2007  
000000023093/Version: 1.2  
Print Date: 02/13/2009  
Page: 3/7  
result to the batteries or electrical equipment. DO NOT RECHARGE. Charging may result in electrolyte  
leakage, explosion and/or cause the battery to flame. Avoid reversing polarity within a device or a battery  
assembly. To do so may cause leakage, explosion, and/or flame.  
Storage: Do not store in a manner that allows terminals to short circuit. Keep in a dry, cool place. Keep  
away from direct sunlight. Storage above 21°C (70°F) may affect product quality. Do not freeze. Keep  
away from water. Short circuiting may reduce battery service life. Extended short circuiting creates high  
temperatures in the battery. High temperatures can cause leakage, explosion, and/or flame. Keep away  
from incompatible substances (see Incompatibility section.)  
8. Exposure controls / personal protection  
Occupational exposure controls  
Chemical Name  
Regulatory List Value Type  
Value  
Manganese dioxide  
OSHA Z1  
Ceiling Limit Value:  
5 mg/m3  
Expressed as Mn  
time weighted average  
Expressed as Mn  
Ceiling Limit Value:  
time weighted average  
ACGIH  
0.2 mg/m3  
Potassium hydroxide  
Graphite  
ACGIH  
ACGIH  
2 mg/m3  
2 mg/m3  
Form of exposure: Respirable fraction.  
Z3  
Remarks: Listed  
OSHA Z1  
OSHA Z1  
Z3  
time weighted average  
5 mg/m3  
Form of exposure: Respirable fraction.  
time weighted average  
Form of exposure: Total dust.  
time weighted average  
15 mg/m3  
15 millions of particles  
per cubic foot of air  
2.5 mg/m3  
OSHA Z1A  
time weighted average  
Form of exposure: Respirable dust.  
Ventilation: Supplemental ventilation may be needed in special circumstances to control fumes/vapours  
to an acceptable level.  
Respiratory protection: None should be needed.  
Eye protection: When handling a damaged battery, wear safety glasses with side shields (or goggles).  
Hand protection: When handling a damaged battery, wear impervious gloves.  
9. Physical and chemical properties  
Physical form: solid  
Colour: not applicable  
Odour: odourless  
Specific gravity: not applicable  
Material Safety Data Sheet  
Revision Date: 10/08/2007  
000000023093/Version: 1.2  
Print Date: 02/13/2009  
Page: 4/7  
Vapour pressure: negligible  
Vapour density: not applicable  
Volatile fraction by weight: not applicable  
Melting point/range: not applicable  
Water solubility: insoluble  
pH: not applicable  
Flash point: not applicable  
10. Stability and reactivity  
Stability: Stable under normal conditions.  
Incompatibility: no data available.  
Hazardous decomposition products: None under normal conditions of use.  
Hazardous Polymerization: Hazardous polymerisation does not occur.  
11. Toxicological information  
Effects of Exposure  
General advice: Since the materials in this battery are sealed in the battery case, the potential for  
exposure to the components of the battery is negligible when the battery is used as directed.  
However, technical or electrical abuse of the battery may result in the release of battery contents.  
Contains: Manganese dioxide. Can cause nervous system damage.  
Inhalation: Intact battery: Expected to be a low hazard for recommended handling. Damaged  
battery: Harmful if inhaled. May cause irritation to the mucous membranes and upper respiratory  
tract.  
Eyes: Intact battery: Expected to be a low hazard for recommended handling. Damaged battery:  
Contact with electrolyte (liquid) causes burns. Airborne dust/mist/vapor irritating. Contact with metal  
fragments may cause burns or mechanical injury.  
Skin: Intact battery: Expected to be a low hazard for recommended handling. Damaged battery:  
Contact with electrolyte (liquid) causes burns. Contact with metal fragments may cause burns or  
mechanical injury. Harmful if absorbed through skin. Vapors or fumes may cause irritation.  
Ingestion: All batteries may be harmful if swallowed. May cause burns of the gastrointestinal tract if  
swallowed.  
Data for Potassium hydroxide (CAS 1310-58-3):  
Material Safety Data Sheet  
Revision Date: 10/08/2007  
000000023093/Version: 1.2  
Print Date: 02/13/2009  
Page: 5/7  
Acute Toxicity Data:  
Oral LD50 (rat): 273 mg/kg  
Skin irritation: severe  
12. Ecological information  
This material is not expected to be harmful to aquatic life.  
13. Disposal considerations  
DO NOT INCINERATE or expose to fire. Discharge, treatment, or disposal may be subject to federal,  
state, commonwealth, provincial, or local laws.  
14. Transport information  
15. Regulatory information  
Notification status  
Regulatory List  
EINECS  
Notification status  
y (positive listing)  
y (positive listing)  
y (positive listing)  
y (positive listing)  
n (Negative listing)  
y (positive listing)  
y (positive listing)  
y (positive listing)  
TSCA  
AICS  
DSL  
ENCS (JP)  
KECI (KR)  
PICCS (PH)  
INV (CN)  
A N (Negative listing) indicates one or more component is either not on the public Inventory or is  
subject to exemption requirements. If additional information is needed contact Kodak.  
Other regulations  
American Conference of Governmental Industrial Hygienists  
(ACGIH):  
No component of this product present at  
levels greater than or equal to 0.1% is  
identified as a carcinogen or potential  
carcinogen by ACGIH.  
International Agency for Research on Cancer (IARC):  
U.S. National Toxicology Program (NTP):  
No component of this product present at  
levels greater than or equal to 0.1% is  
identified as probable, possible or  
confirmed human carcinogen by IARC.  
No component of this product present at  
levels greater than or equal to 0.1% is  
identified as a known or anticipated  
Material Safety Data Sheet  
Revision Date: 10/08/2007  
000000023093/Version: 1.2  
Print Date: 02/13/2009  
Page: 6/7  
carcinogen by NTP.  
U.S. Occupational Safety and Health Administration (OSHA):  
No component of this product present at  
levels greater than or equal to 0.1% is  
identified as a carcinogen or potential  
carcinogen by OSHA.  
California Prop. 65:  
none  
US. EPA Emergency Planning and Community Right-To-Know Act  
(EPCRA) SARA Title III Section 313 Toxic Chemicals (40 CFR  
372.65) - Supplier Notification Required:  
Manganese dioxide, Zinc  
US. EPA Emergency Planning and Community Right-To-Know Act  
(EPCRA) SARA Title III Section 302 Extremely Hazardous  
Substance (40 CFR 355, Appendix A):  
SARA 302: No chemicals in this material  
are subject to the reporting  
requirements of SARA Title III, Section  
302.  
US. Pennsylvania Worker and Community Right-to-Know Law (34  
Pa. Code Chap. 301-323):  
Manganese dioxide, Zinc, Potassium  
hydroxide, Water, Graphite  
US. Massachusetts Commonwealth's Right-to-Know Law  
(Appendix A to 105 Code of Massachusetts Regulations  
Section 670.000):  
Zinc, Graphite  
US. New Jersey Worker and Community Right-to-Know Act (New  
Jersey Statute Annotated Section 34:5A-5):  
Manganese dioxide, Zinc, Potassium  
hydroxide, Water, Graphite  
16. Other information  
The data below reflects current legislative requirements whereas the product in your possession may  
carry a different version of the label depending on the date of manufacture.  
US/Canadian Label Statements:  
CONTAINS: Manganese dioxide (1313-13-9), Zinc (7440-66-6), Potassium hydroxide (1310-58-  
3), Graphite (7782-42-5)  
WARNING!  
MAY FLAME OR LEAK IF OPENED, SHORT CIRCUITED, RECHARGED, CONNECTED  
IMPROPERLY, OR EXPOSED TO FIRE OR HIGH TEMPERATURES.  
HARMFUL IF SWALLOWED  
VAPORS/FUMES FROM DAMAGED BATTERIES MAY CAUSE RESPIRATORY TRACT  
IRRITATION  
DAMAGED BATTERIES MAY CAUSE SKIN AND EYE BURNS  
FIRST AID: If vapours or fumes from vented or leaking battery are irritating to respiratory tract, move  
to fresh air. Get medical attention if symptoms occur. In case of contact with battery contents (liquid  
or metal), immediately flush with plenty of water for at least 15 minutes. Get medical attention  
immediately. In case of contact with battery contents (liquid or metal), immediately remove metal  
fragments and flush skin with plenty of water for at least 15 minutes while removing contaminated  
clothing and shoes. Wash contaminated clothing before re-use. Destroy or thoroughly clean  
contaminated shoes. Get medical attention immediately. All batteries may be harmful if swallowed.  
Call a physician or poison control center immediately for any actual or suspected ingestion. If  
swallowed, DO NOT induce vomiting. Batteries may lodge in the throat or digestive tract and  
fragment. If battery was leaking or was chewed, rinse mouth thoroughly with water.  
Material Safety Data Sheet  
Revision Date: 10/08/2007  
000000023093/Version: 1.2  
Print Date: 02/13/2009  
Page: 7/7  
Keep out of reach of children.  
Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read  
and understood.  
Since emptied containers retain product residue, follow label warnings even after container is  
emptied.  
IN CASE OF FIRE: Use appropriate agent for adjacent fire.  
IN CASE OF SPILL: Dispose of in accordance with local regulations (see Section 13. Disposal  
considerations). For Large Spills: None should be needed.  
The information contained herein is furnished without warranty of any kind. Users should consider these  
data only as a supplement to other information gathered by them and must make independent  
determinations of suitability and completeness of information from all sources to assure proper use and  
disposal of these materials and the safety and health of employees and customers and the protection of  
the environment. The information relating to the working solution is for guidance purposes only, and is  
based on correct mixing and use of the product according to instructions.  

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